Table 3. Occupation Numbers n of the LUNO, LUNO+1, and LUNO+2 to Quantify the Bi- and Tetraradical Character for 1H in Comparison with E.
compound | active space | n(LUNO) | n(LUNO+1) | n(LUNO+2) |
---|---|---|---|---|
Ea | CASSCF(2,2) | 0.18 | ||
CASSCF(10,9) | 0.21 | 0.09 | 0.09 | |
1H | CASSCF(4,4) | 0.26 | 0.19 | |
CASSCF(14,12) | 0.32 | 0.19 | 0.09 |
Values taken from ref (43).