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. 2023 Jul 26;13(32):22579–22592. doi: 10.1039/d3ra02912c

Temperature dependent catalyst deactivation model.

Deferential form Integral form Catalyst TOS Reactor type Reaction Reference
nta a = eαtos FCC catalyst 90 s Fixed bed reactor VGO catalytic cracking Ebrahimi et al.18
graphic file with name d3ra02912c-t12.jpg FCC catalyst nta Fixed and fluidized bed VGO pyrolysis Naik et al.43
nta a = (1 − kdt) Pt/Al2O3 nta Fixed bed reactor Dehydrogenation methylcyclohexane Usman et al.69
graphic file with name d3ra02912c-t13.jpg a = ekdt Pt–Sn/Al2O3 100 h Fixed bed reactor Propane dehydrogenation Zangeneh et al.44
nta 10–10000 h Packed-bed reactor Hydrogenation of CO2 Sun et al.45
FCC catalyst 2–10 s FCC reactor Vacuum gas oil (VGO) catalytic cracking Sani et al.46
TS-1/SiO2 1–24 h Fixed-bed reactor Epoxidation of allyl chloride with hydrogen peroxide Lin et al.47
nta nta Fixed-bed reactor Ethanol dehydration Demuner et al.48
Pt/Al2O3 1225 day Fixed bed reactor Heavy naphtha reforming Shakor et al.20
graphic file with name d3ra02912c-t14.jpg graphic file with name d3ra02912c-t15.jpg Pd–Ag/a-Al2O3 120 h Fixed bed reactor Selective hydrogenation of acetylene to ethylene Ravanchi et al.49
graphic file with name d3ra02912c-t16.jpg graphic file with name d3ra02912c-t17.jpg Cu/AC 12 h Fixed bed reactor Acetylene hydrochlorination Xu et al.70
nta graphic file with name d3ra02912c-t18.jpg NiMo/Al2O3 0–550 h Continuous stirred tank basket reactor (CSTBR) Hydrocracking of heavy oil Martínez and Ancheyta67
graphic file with name d3ra02912c-t19.jpg graphic file with name d3ra02912c-t20.jpg H2O2 with TS-1/SiO2 0–50 h Fixed-bed reactor Liquid phase propylene epoxidation Feng et al.71
Nanocrystalline zeolite beta 0–6 h Fixed-bed micro-reactor Catalytic cracking of used palm oil Taufiqurrahmi et al.72
Pd/carbon 0–400 Fixed bed reactor Crude terephthalic acid hydro-purification Li et al.73
Ni–Al oxide 0–165 h Fixed bed reactors CO2 methanation Ewald et al.65
brewer's spent yeast (BSY) 120 min Batch reactor Biodiesel production from FFA Arumugamurthy et al.66
Ni based catalyst 0–900 day Membrane reformer Methane reforming Jokar et al.74
Ni/Al2O3 0–100 h Fixed bed reactors CO2 methanation Morosanu et al.75
HY-zeolites 5 min Packed bed reactor Dehydration of glycerol to acrolein Pala-Rosas et al.76
graphic file with name d3ra02912c-t21.jpg nta SBA-15 500 min Fixed bed reactor Methane decomposition Chen and Lua50
graphic file with name d3ra02912c-t22.jpg nta Pt/Al2O3 0–350 h nta nta Bartholomew51
graphic file with name d3ra02912c-t23.jpg a = a + (1 − a)ekdt Cobalt based catalyst 0–1000 h Bubble-column reactor Fischer–Tropsch Argyle et al.52
Chiral 0–242.2 h Batch reactor Hydrogenation of acetophenone Ruelas-Leyva & Fuentes53
graphic file with name d3ra02912c-t24.jpg graphic file with name d3ra02912c-t25.jpg Fe/Al2O3 0–1300 h Slurry bubble column reactor Fischer–Tropsch Ghofran et al.54
graphic file with name d3ra02912c-t26.jpg nta CuO/ZnO/Al2O3 nta nta nta Honken56
graphic file with name d3ra02912c-t27.jpg nta Pt/Re/Al2O3 0–800 day Spherical packed-bed reactor Naphtha reforming Rahimpour et al.64
nta Pt/Re/Al2O3 0–800 day Spherical packed-bed reactor Naphtha reforming Iranshahi et al.68
a

Not reported.