Table 2. Obtained Isotherm Parameters for Adsorption of Pb2+ and Cd2+ Ions over Fe–MOF and Cox–Fe1–x–MOFs.
Langmuir
isotherm |
Freundlich
isotherm |
|||||||
---|---|---|---|---|---|---|---|---|
metal ion | sample | qm (mg/g) | KL (L/mg) | R2 | RL | KF (mg/g) | n | R2 |
Pb2+ | Fe–MOF | 120.8 | 0.06 | 0.9805 | 0.14 | 24.32 | 2.61 | 0.9926 |
Co0.25–Fe0.75–MOF | 179.2 | 0.26 | 0.9908 | 0.04 | 33.54 | 2.30 | 0.9231 | |
Co0.50–Fe0.50–MOF | 198.6 | 0.44 | 0.9964 | 0.02 | 38.63 | 2.13 | 0.9183 | |
Co0.75–Fe0.25–MOF | 169.3 | 0.16 | 0.9903 | 0.06 | 33.40 | 2.34 | 0.9231 | |
Cd2+ | Fe–MOF | 115.3 | 0.03 | 0.9974 | 0.33 | 12.9 | 1.97 | 0.9698 |
Co0.25–Fe0.75–MOF | 170.8 | 0.13 | 0.9956 | 0.08 | 49.9 | 2.49 | 0.9729 | |
Co0.50–Fe0.50–MOF | 183.5 | 0.19 | 0.9851 | 0.05 | 70.2 | 2.99 | 0.9789 | |
Co0.75–Fe0.25–MOF | 152.9 | 0.05 | 0.9905 | 0.20 | 28.2 | 1.99 | 0.9882 |