Table 3. Kinetic Parameters Obtained from the Pseudo-First-Order and Pseudo-Second-Order Fitting on the Adsorption Process of Pb2+ and Cd2+ over Fe–MOF and Cox–Fe1–x–MOFs.
qe(Exp) (mg/g) | pseudo-first-order |
pseudo-second-order |
||||||
---|---|---|---|---|---|---|---|---|
metal ions | sample | qe1 (mg/g) | K1 | R2 | qe2 (mg/g) | K2 × 10–4 | R2 | |
Pb2+ | Fe–MOF | 118.4 | 220.17 | 0.025 | 0.9526 | 121.6 | 7.36 | 0.9891 |
Co0.25–Fe0.75–MOF | 177.5 | 302.48 | 0.036 | 0.9883 | 176.2 | 9.44 | 0.9926 | |
Co0.50–Fe0.50–MOF | 193.4 | 358.53 | 0.041 | 0.9714 | 201.3 | 17.79 | 0.9968 | |
Co0.75–Fe0.25–MOF | 168.1 | 404.64 | 0.033 | 0.9132 | 162.2 | 12.29 | 0.9929 | |
Cd2+ | Fe–MOF | 111.5 | 260.8 | 0.019 | 0.8382 | 123.1 | 3.6 | 0.9977 |
Co0.25–Fe0.75–MOF | 169.3 | 429.8 | 0.035 | 0.9659 | 187.2 | 83.6 | 0.9926 | |
Co0.50–Fe0.50–MOF | 182.2 | 597.3 | 0.039 | 0.9713 | 195.3 | 92.9 | 0.9968 | |
Co0.75–Fe0.25–MOF | 154.5 | 962.9 | 0.050 | 0.9715 | 172.1 | 1.6 | 0.9881 |