Table 2. Thermal Decomposition of the Prepared Complexes.
TG (°C) | DTG (°C) | mass loss (%) |
assignment | residue | ||
---|---|---|---|---|---|---|
found | calculated | |||||
CrAz2 | 30–430 | 215 | 53.84 | 53.76 | 1H2O + C20H14O2Cl | Cr |
430–650 | 520 | 38.22 | 38.01 | C12H8O2N4 | ||
MnAz2 | 30–420 | 295 | 52.29 | 52.19 | 2H2O + C20H14O2 | Mn |
420–640 | 530 | 39.13 | 38.90 | C12H8O2N4 | ||
FeAz2 | 30–440 | 255 | 53.24 | 53.42 | 1H2O + C20H14O2Cl | Fe |
440–680 | 540 | 37.91 | 37.77 | C12H8O2N4 |