Table 3. The Integrated Thermal Desorption Profile Peak Areas (PAs) of Detected Pesticides in Different Sample Matrices and the Corresponding Quantitative Results Gained with Validated Methods.

	Formula	adduct	peak area	quantitative detection (mg/kg)a
Watermelon extract
dimethomorph	C21H22ClNO4	[M+H]+	8.79E2	0.010
dinotefuran	C7H15N4O3+	[M+Br]−	2.41E3	0.011
imazalil	C14H14N2Cl2O	[M+H]+	1.12E4	0.83
Lime extract
azoxystrobin	C22H17N3O5	[M+H]+	1.74E3	0.022
imazalil	C14H14N2Cl2O	[M+H]+	1.09E5	1.5
Avocado extract
thiabendazole	C10H7N3S	[M+H]+	1.57E5	0.51
Pineapple extract
fludioxonil	C12H6F2N2O2	[M+Br]−	5.35E5	0.48
diazinonb	C12H21N2O3PS	[M+H]+	1.1E3	0.011
Pineapple swabbingc
fludioxonil	C12H6F2N2O2	[M+Br]−	4.2E5	0.48
diazinon	C12H21N2O3PS	[M+H]+	7.9E2	0.011
Pineapple juice
fludioxonil	C12H6F2N2O2	[M+Br]−	4.4E3	0.48
diazinon	C12H21N2O3PS	[M+H]+	1.1E2	0.011

^aQuantitative detection presents the concentrations reported in mg/kg, which are correlated with the concentrations obtained from standardized measurements performed on the same samples by the Finnish Customs.

^bThe measurement of pineapple extract in positive mode was conducted by injecting 5 μL of the fruit extract.

^cThe pesticide content of the pineapple fruit swab is reported in relation to the whole pesticide content of the fruit determined by the Finnish Customs using the standardized procedures. This approach was followed as the actual pesticide amount present in the surface of the fruit was unknown.