Table 1.
Electronic spectral data in acetonitrile for H2L and Ni(II)L and their calibration curves.
| Compound | Band Maxima (cm−1) | Wavelength (nm) | Assignment | Calibration Equation/Figure (C in µM) |
|---|---|---|---|---|
| H2L | 37,175 | 269 | n→π* | Abs2 = −0.0573 + 0.0416·C/Figure 17b |
| 30,215 | 331 | π→π* | Abs1 = −0.0422 + 0.0318·C/Figure 17b | |
| Ni(II)L | 38,911 | 257 | π→π* | Abs3 = −0.0546 + 0.0581·C/Figure 18b |
| 26,738 | 373 | n→π* | Abs2 = −0.0308+ 0.0329·C/Figure 18b | |
| 21,097 | 474 | 1A1g→1B1g | Abs1 = −0.0095 + 0.0108·C/Figure 18b |