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Results for genetic optimization using [Cp*Ir(Boc-AQ-biot)Cl] 10: (a) TON and (b) ee for reactions using single mutants at positions S112X or K121X′; (c) TON and (d) ee for reactions using double mutants Sav S112I-K121X′. Results for reactions using single mutants Sav S112X, Sav K121X′ and double mutants Sav S112I-K121X′ are highlighted in blue, red, and violet, respectively. Double mutants Sav S112I-K121X′ are abbreviated as IX′ in (c) and (d).
