Summary of synthetic conditions and assembled productsa.
| Product formula | Metal(ii) precursor | ALb | M2+/linker/AL/NaOH molar ratio | Dimensi-onality |
|---|---|---|---|---|
| [Cu2(μ2-mia)2(phen)2(H2O)2]·2H2O (1) | CuCl2·2H2O | Phen | 1/1/1/2 | 0D |
| [Mn(μ3-mia)(phen)]n (2) | MnCl2·4H2O | Phen | 1/1/1/2 | 1D |
| [Co(μ2-mia)(2,2′-bipy)(H2O)]n·nH2O (3) | CoCl2·6H2O | 2,2′-Bipy | 1/1/1/2 | 1D |
| [Co(μ3-mia)(μ2-4,4′-bipy)]n·nH2O (4) | CoCl2·6H2O | 4,4′-Bipy | 1/1/1/2 | 2D |
| [Co(μ3-mia)(py)2]n (5) | CoCl2·6H2O | py | 1/1/31/— | 1D |
| [Cd(μ2-mia)(py)(H2O)2]n·nH2On (6) | CdCl2·H2O | py | 1/1/31/— | 1D |
a
Hydrothermal synthesis: stainless steel reactor (25 mL volume; Teflon-lined), MCl2 (0.2 mmol), H2O (10 mL), 3 days at 160 °C, 10 °C h−1 cooling rate.
b
AL, N-donor auxiliary ligand. The oxidation state of the metals in compounds 1–5 was determined by the values of magnetic moment (Fig. S3 and Table S3).