Table 3.
Thermodynamic parameters of the reactions of conventional and protein pretreatment enzymatic digestion.
| Type | Ea (kJ/mol) | ΔH (kJ/mol) | ΔS (J/mol·K) |
ΔG (J/mol·K) |
|||
|---|---|---|---|---|---|---|---|
| 20 °C | 30 °C | 40 °C | 50 °C | ||||
| Control | 10.17 ± 0.012a | 82.01 ± 0.104a | –17.42 ± 0.42a | 5.18 ± 0.11c | 5.36 ± 0.12c | 5.53 ± 0.12c | 5.70 ± 0.13c |
| HT | 8.42 ± 0.056b | 67.44 ± 0.46b | –60.18 ± 1.29b | 17.71 ± 0.38b | 18.31 ± 0.39b | 18.91 ± 0.40b | 19.51 ± 0.42b |
| US | 8.23 ± 0.12b | 65.89 ± 0.97b | –65.27 ± 2.95c | 19.20 ± 0.86a | 19.85 ± 0.89a | 20.51 ± 0.92a | 21.16 ± 0.95a |
| HT + US | 8.00 ± 0.035b | 63.98 ± 0.29c | –69.14 ± 1.08c | 20.33 ± 0.32a | 21.02 ± 0.33a | 21.71 ± 0.34a | 22.411 ± 0.35a |
Significant differences (P < 0.05) between sample points for different lowercase letters in the upper-right corner of the data are shown in the same column as Table 3.