Table 7. Potentiodynamic Polarization Data for Carbon Steel in 1.0 M HCl with and without KI and Inhibitors + KI at 25 °C.
| inhibitors | conc. (M) | –Ecorr (Mv) | icorr (μA cm2) | βc (mV dec–1) | βa (mV dec–1) | corrosion rate (CR) (mp y–1) | θ | %IE |
|---|---|---|---|---|---|---|---|---|
| CMBTAP | blank (1.0 M HCl) | 420 | 118.5 | 125.77 | 86.8 | 55.36 | ||
| 0.01 M KI | 443.7 | 66.4 | 101.85 | 93.66 | 30.59 | 0.428 | 22.8 | |
| 1 × 10–5 + 0.01 M KI | 448 | 23.2 | 95.04 | 107.7 | 10.93 | 0.804 | 80.4 | |
| 5 × 10–5 + 0.01 M KI | 464 | 19.09 | 64.32 | 107.5 | 8.5 | 0.838 | 83.8 | |
| 10 × 10–5 + 0.01 M KI | 446 | 17.42 | 64.2 | 104.2 | 7.75 | 0.853 | 85.3 | |
| 15 × 10–5 + 0.01 M KI | 472 | 14.23 | 58.5 | 96.4 | 5.25 | 0.879 | 87.9 | |
| 20 × 10–5 + 0.01 M KI | 476 | 8.1 | 63.6 | 100.8 | 3.75 | 0.932 | 93.2 | |
| CBAN | 1 × 10–5 + 0.01 M KI | 446 | 36.5 | 102.5 | 96.2 | 18.9 | 0.692 | 69.2 |
| 5 × 10–5 + 0.01 M KI | 453 | 28.1 | 81.1 | 94.3 | 14.1 | 0.763 | 76.3 | |
| 10 × 10–5 + 0.01 M KI | 462 | 25.9 | 80.5 | 110.6 | 12.1 | 0.782 | 78.2 | |
| 15 × 10–5 + 0.01 M KI | 465 | 23.5 | 70.0 | 106.3 | 11.2 | 0.80 | 80 | |
| 20 × 10–5 + 0.01 M KI | 451 | 18.8 | 60.3 | 74.7 | 8.74 | 0.842 | 84.2 | |
| CBAMP | 1 × 10–5 + 0.01 M KI | 445 | 24.4 | 77.9 | 96.9 | 11.3 | 0.795 | 79.5 |
| 5 × 10–5 + 0.01 M KI | 453 | 21.6 | 71.5 | 107.8 | 10.1 | 0.82 | 82 | |
| 10 × 10–5 + 0.01 M KI | 461 | 19.7 | 83.0 | 102.4 | 8.95 | 0.834 | 83.4 | |
| 15 × 10–5 + 0.01 M KI | 466 | 14.3 | 65.1 | 88.6 | 6.8 | 0.879 | 87.9 | |
| 20 × 10–5 + 0.01 M KI | 470 | 11.5 | 50.5 | 76.0 | 5.3 | 0.905 | 90.5 |