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cYY-induced modulation of the CYP121 proximal surface.19F-NMR Spectra acquired in the presence of two-fold excess cYY result in the introduction of a new peak at −84.3 ppm for CYP121_T103C (A). However, in the case of CYP121_T333C, only changes in the paramagnetic pseudocontact shifts are observed (B).
