Table 6. Experimental Speeds of Sound, w, for R1234yf (2,3,3,3-Tetrafluoroprop-1-ene), with the Combined Expanded (k = 2) Relative Uncertainty in the Speed of Sound, Uc, Also Given along with Relative Deviations from the Equation of State of Lemmon and Akasaka41a,b.
T (K) | P (MPa) | W (m·s–1) | Uc (k = 2) (%) | 100(w/wEOS – 1) |
---|---|---|---|---|
260.090 | 0.641 | 617.92 | 0.055 | 0.034 |
265.117 | 0.638 | 595.66 | 0.058 | 0.067 |
270.098 | 1.895 | 585.39 | 0.059 | 0.059 |
275.100 | 5.020 | 592.64 | 0.056 | 0.033 |
280.107 | 8.149 | 599.84 | 0.054 | 0.015 |
290.111 | 14.430 | 614.11 | 0.050 | –0.012 |
300.105 | 20.638 | 627.61 | 0.047 | –0.016 |
310.108 | 26.784 | 640.41 | 0.045 | –0.011 |
320.146 | 32.869 | 652.60 | 0.043 | –0.001 |
330.159 | 38.879 | 664.28 | 0.041 | 0.006 |
280.103 | 1.080 | 533.39 | 0.071 | 0.058 |
285.089 | 3.892 | 541.30 | 0.067 | 0.035 |
290.106 | 6.728 | 549.09 | 0.063 | 0.014 |
295.105 | 9.540 | 556.58 | 0.060 | 0.001 |
300.105 | 12.350 | 563.88 | 0.057 | –0.008 |
310.109 | 17.923 | 577.75 | 0.053 | –0.010 |
320.133 | 23.485 | 591.08 | 0.050 | –0.004 |
330.123 | 28.982 | 603.71 | 0.047 | 0.003 |
340.118 | 34.401 | 615.63 | 0.045 | 0.017 |
350.119 | 39.760 | 627.01 | 0.043 | 0.028 |
360.126 | 45.057 | 637.89 | 0.042 | 0.035 |
370.138 | 50.278 | 648.27 | 0.040 | 0.037 |
300.100 | 0.715 | 437.61 | 0.109 | –0.016 |
305.118 | 0.821 | 415.20 | 0.123 | –0.059 |
310.104 | 0.938 | 392.78 | 0.140 | –0.108 |
315.115 | 1.068 | 370.05 | 0.161 | –0.162 |
320.127 | 2.166 | 365.95 | 0.161 | –0.116 |
330.125 | 5.839 | 384.76 | 0.130 | –0.025 |
340.116 | 9.517 | 401.52 | 0.108 | –0.009 |
350.135 | 13.197 | 416.80 | 0.094 | 0.003 |
360.143 | 16.855 | 430.86 | 0.083 | 0.019 |
319.979 | 1.289 | 349.60 | 0.185 | –0.174 |
324.983 | 3.063 | 359.82 | 0.163 | –0.071 |
329.992 | 4.846 | 369.35 | 0.146 | –0.023 |
334.981 | 6.621 | 378.20 | 0.132 | –0.010 |
339.983 | 8.403 | 386.62 | 0.121 | –0.007 |
344.992 | 10.185 | 394.64 | 0.111 | 0.000 |
349.990 | 11.966 | 402.33 | 0.103 | 0.004 |
355.010 | 13.754 | 409.76 | 0.095 | 0.007 |
359.996 | 15.527 | 416.85 | 0.089 | 0.015 |
235.010 | 0.637 | 729.97 | 0.043 | –0.050 |
240.002 | 0.734 | 708.26 | 0.045 | –0.023 |
245.003 | 4.676 | 714.03 | 0.044 | –0.032 |
250.005 | 8.663 | 720.22 | 0.043 | –0.036 |
254.995 | 12.624 | 726.36 | 0.042 | –0.035 |
259.990 | 16.592 | 732.57 | 0.041 | –0.033 |
250.001 | 1.049 | 666.04 | 0.049 | 0.004 |
254.996 | 4.746 | 672.67 | 0.047 | –0.012 |
259.990 | 8.460 | 679.43 | 0.046 | –0.024 |
264.997 | 12.253 | 686.64 | 0.044 | –0.038 |
269.992 | 15.942 | 693.26 | 0.043 | –0.032 |
259.988 | 1.012 | 621.58 | 0.054 | 0.031 |
264.995 | 4.401 | 628.57 | 0.052 | 0.007 |
269.992 | 7.791 | 635.56 | 0.050 | –0.010 |
274.996 | 11.181 | 642.49 | 0.048 | –0.019 |
280.000 | 14.563 | 649.33 | 0.047 | –0.023 |
269.990 | 1.011 | 577.43 | 0.061 | 0.049 |
274.995 | 4.113 | 584.90 | 0.058 | 0.022 |
280.000 | 7.177 | 591.96 | 0.056 | 0.009 |
285.002 | 10.248 | 598.98 | 0.053 | –0.005 |
290.020 | 13.339 | 606.04 | 0.051 | –0.011 |
279.999 | 1.014 | 533.15 | 0.071 | 0.059 |
285.001 | 3.836 | 541.08 | 0.067 | 0.034 |
290.004 | 6.660 | 548.85 | 0.063 | 0.016 |
294.999 | 9.483 | 556.46 | 0.060 | 0.004 |
300.000 | 12.305 | 563.88 | 0.057 | –0.003 |
290.002 | 1.002 | 488.16 | 0.085 | 0.045 |
294.998 | 3.566 | 496.79 | 0.079 | 0.030 |
300.003 | 6.159 | 505.32 | 0.074 | 0.007 |
305.000 | 8.776 | 513.87 | 0.069 | –0.002 |
310.001 | 11.331 | 521.56 | 0.065 | 0.000 |
289.998 | 1.065 | 488.94 | 0.085 | 0.042 |
294.995 | 3.618 | 497.39 | 0.079 | 0.030 |
299.997 | 6.182 | 505.63 | 0.073 | 0.015 |
304.996 | 8.743 | 513.59 | 0.069 | 0.006 |
309.999 | 11.304 | 521.30 | 0.065 | 0.000 |
299.996 | 1.063 | 443.13 | 0.105 | 0.000 |
304.996 | 3.365 | 452.31 | 0.096 | 0.005 |
310.002 | 5.680 | 461.14 | 0.089 | –0.001 |
314.994 | 7.997 | 469.68 | 0.082 | –0.001 |
320.002 | 10.294 | 477.62 | 0.077 | –0.002 |
309.996 | 1.242 | 398.58 | 0.134 | –0.061 |
314.993 | 3.278 | 408.13 | 0.121 | –0.023 |
320.003 | 5.328 | 417.23 | 0.110 | –0.007 |
325.008 | 7.377 | 425.86 | 0.101 | –0.001 |
329.998 | 9.417 | 434.05 | 0.093 | 0.004 |
320.001 | 1.356 | 351.05 | 0.183 | –0.112 |
325.006 | 3.135 | 361.18 | 0.161 | –0.027 |
330.014 | 4.921 | 370.57 | 0.144 | –0.010 |
335.002 | 6.722 | 379.65 | 0.130 | –0.016 |
340.006 | 8.495 | 387.97 | 0.119 | 0.025 |
330.012 | 1.732 | 306.16 | 0.256 | –0.207 |
335.000 | 3.267 | 316.98 | 0.221 | –0.016 |
340.007 | 4.814 | 327.03 | 0.193 | 0.106 |
345.011 | 6.373 | 336.21 | 0.172 | 0.084 |
350.008 | 7.969 | 345.18 | 0.153 | –0.019 |
289.995 | 1.008 | 488.27 | 0.085 | 0.044 |
294.990 | 3.578 | 496.95 | 0.079 | 0.028 |
299.991 | 6.155 | 505.37 | 0.074 | 0.016 |
309.992 | 1.278 | 399.22 | 0.133 | –0.054 |
319.997 | 5.380 | 418.02 | 0.109 | 0.001 |
329.995 | 9.489 | 434.97 | 0.093 | 0.008 |
340.005 | 13.584 | 450.38 | 0.081 | 0.017 |
350.007 | 17.663 | 464.70 | 0.073 | 0.029 |
359.997 | 21.713 | 478.08 | 0.066 | 0.050 |
369.991 | 25.751 | 490.77 | 0.061 | 0.068 |
289.991 | 0.994 | 488.14 | 0.085 | 0.052 |
294.989 | 3.557 | 496.76 | 0.079 | 0.038 |
299.991 | 6.128 | 505.12 | 0.074 | 0.025 |
304.991 | 8.697 | 513.20 | 0.069 | 0.015 |
309.993 | 11.264 | 521.00 | 0.066 | 0.010 |
329.995 | 1.753 | 307.02 | 0.255 | –0.132 |
340.003 | 4.867 | 328.07 | 0.192 | 0.100 |
350.006 | 7.987 | 345.96 | 0.153 | 0.117 |
359.996 | 11.113 | 361.70 | 0.127 | 0.023 |
369.991 | 14.242 | 376.38 | 0.109 | 0.019 |
380.020 | 17.378 | 390.06 | 0.095 | 0.027 |
289.992 | 1.010 | 488.35 | 0.085 | 0.054 |
294.990 | 3.561 | 496.83 | 0.079 | 0.042 |
299.987 | 6.117 | 505.04 | 0.074 | 0.029 |
304.990 | 8.666 | 512.92 | 0.069 | 0.022 |
309.993 | 11.224 | 520.64 | 0.066 | 0.016 |
The listed data are averaged from 12 measured echo-delay times (4 sets of 3 replicates each); see Supporting Information for unaveraged data. The data are listed in the order measured; blank lines separate measured isochores.
The standard (k = 1) uncertainties in T and p are 0.005 K and (26 × 10–6·p + 0.016 MPa), respectively.