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. 2023 Jul 28;62(31):12381–12406. doi: 10.1021/acs.iecr.3c01720

Table 6. Experimental Speeds of Sound, w, for R1234yf (2,3,3,3-Tetrafluoroprop-1-ene), with the Combined Expanded (k = 2) Relative Uncertainty in the Speed of Sound, Uc, Also Given along with Relative Deviations from the Equation of State of Lemmon and Akasaka41a,b.

T (K) P (MPa) W (m·s–1) Uc (k = 2) (%) 100(w/wEOS – 1)
260.090 0.641 617.92 0.055 0.034
265.117 0.638 595.66 0.058 0.067
270.098 1.895 585.39 0.059 0.059
275.100 5.020 592.64 0.056 0.033
280.107 8.149 599.84 0.054 0.015
290.111 14.430 614.11 0.050 –0.012
300.105 20.638 627.61 0.047 –0.016
310.108 26.784 640.41 0.045 –0.011
320.146 32.869 652.60 0.043 –0.001
330.159 38.879 664.28 0.041 0.006
       
280.103 1.080 533.39 0.071 0.058
285.089 3.892 541.30 0.067 0.035
290.106 6.728 549.09 0.063 0.014
295.105 9.540 556.58 0.060 0.001
300.105 12.350 563.88 0.057 –0.008
310.109 17.923 577.75 0.053 –0.010
320.133 23.485 591.08 0.050 –0.004
330.123 28.982 603.71 0.047 0.003
340.118 34.401 615.63 0.045 0.017
350.119 39.760 627.01 0.043 0.028
360.126 45.057 637.89 0.042 0.035
370.138 50.278 648.27 0.040 0.037
       
300.100 0.715 437.61 0.109 –0.016
305.118 0.821 415.20 0.123 –0.059
310.104 0.938 392.78 0.140 –0.108
315.115 1.068 370.05 0.161 –0.162
320.127 2.166 365.95 0.161 –0.116
330.125 5.839 384.76 0.130 –0.025
340.116 9.517 401.52 0.108 –0.009
350.135 13.197 416.80 0.094 0.003
360.143 16.855 430.86 0.083 0.019
       
319.979 1.289 349.60 0.185 –0.174
324.983 3.063 359.82 0.163 –0.071
329.992 4.846 369.35 0.146 –0.023
334.981 6.621 378.20 0.132 –0.010
339.983 8.403 386.62 0.121 –0.007
344.992 10.185 394.64 0.111 0.000
349.990 11.966 402.33 0.103 0.004
355.010 13.754 409.76 0.095 0.007
359.996 15.527 416.85 0.089 0.015
       
235.010 0.637 729.97 0.043 –0.050
240.002 0.734 708.26 0.045 –0.023
245.003 4.676 714.03 0.044 –0.032
250.005 8.663 720.22 0.043 –0.036
254.995 12.624 726.36 0.042 –0.035
259.990 16.592 732.57 0.041 –0.033
       
250.001 1.049 666.04 0.049 0.004
254.996 4.746 672.67 0.047 –0.012
259.990 8.460 679.43 0.046 –0.024
264.997 12.253 686.64 0.044 –0.038
269.992 15.942 693.26 0.043 –0.032
       
259.988 1.012 621.58 0.054 0.031
264.995 4.401 628.57 0.052 0.007
269.992 7.791 635.56 0.050 –0.010
274.996 11.181 642.49 0.048 –0.019
280.000 14.563 649.33 0.047 –0.023
       
269.990 1.011 577.43 0.061 0.049
274.995 4.113 584.90 0.058 0.022
280.000 7.177 591.96 0.056 0.009
285.002 10.248 598.98 0.053 –0.005
290.020 13.339 606.04 0.051 –0.011
       
279.999 1.014 533.15 0.071 0.059
285.001 3.836 541.08 0.067 0.034
290.004 6.660 548.85 0.063 0.016
294.999 9.483 556.46 0.060 0.004
300.000 12.305 563.88 0.057 –0.003
       
290.002 1.002 488.16 0.085 0.045
294.998 3.566 496.79 0.079 0.030
300.003 6.159 505.32 0.074 0.007
305.000 8.776 513.87 0.069 –0.002
310.001 11.331 521.56 0.065 0.000
       
289.998 1.065 488.94 0.085 0.042
294.995 3.618 497.39 0.079 0.030
299.997 6.182 505.63 0.073 0.015
304.996 8.743 513.59 0.069 0.006
309.999 11.304 521.30 0.065 0.000
       
299.996 1.063 443.13 0.105 0.000
304.996 3.365 452.31 0.096 0.005
310.002 5.680 461.14 0.089 –0.001
314.994 7.997 469.68 0.082 –0.001
320.002 10.294 477.62 0.077 –0.002
       
309.996 1.242 398.58 0.134 –0.061
314.993 3.278 408.13 0.121 –0.023
320.003 5.328 417.23 0.110 –0.007
325.008 7.377 425.86 0.101 –0.001
329.998 9.417 434.05 0.093 0.004
       
320.001 1.356 351.05 0.183 –0.112
325.006 3.135 361.18 0.161 –0.027
330.014 4.921 370.57 0.144 –0.010
335.002 6.722 379.65 0.130 –0.016
340.006 8.495 387.97 0.119 0.025
       
330.012 1.732 306.16 0.256 –0.207
335.000 3.267 316.98 0.221 –0.016
340.007 4.814 327.03 0.193 0.106
345.011 6.373 336.21 0.172 0.084
350.008 7.969 345.18 0.153 –0.019
       
289.995 1.008 488.27 0.085 0.044
294.990 3.578 496.95 0.079 0.028
299.991 6.155 505.37 0.074 0.016
       
309.992 1.278 399.22 0.133 –0.054
319.997 5.380 418.02 0.109 0.001
329.995 9.489 434.97 0.093 0.008
340.005 13.584 450.38 0.081 0.017
350.007 17.663 464.70 0.073 0.029
359.997 21.713 478.08 0.066 0.050
369.991 25.751 490.77 0.061 0.068
       
289.991 0.994 488.14 0.085 0.052
294.989 3.557 496.76 0.079 0.038
299.991 6.128 505.12 0.074 0.025
304.991 8.697 513.20 0.069 0.015
309.993 11.264 521.00 0.066 0.010
       
329.995 1.753 307.02 0.255 –0.132
340.003 4.867 328.07 0.192 0.100
350.006 7.987 345.96 0.153 0.117
359.996 11.113 361.70 0.127 0.023
369.991 14.242 376.38 0.109 0.019
380.020 17.378 390.06 0.095 0.027
       
289.992 1.010 488.35 0.085 0.054
294.990 3.561 496.83 0.079 0.042
299.987 6.117 505.04 0.074 0.029
304.990 8.666 512.92 0.069 0.022
309.993 11.224 520.64 0.066 0.016
a

The listed data are averaged from 12 measured echo-delay times (4 sets of 3 replicates each); see Supporting Information for unaveraged data. The data are listed in the order measured; blank lines separate measured isochores.

b

The standard (k = 1) uncertainties in T and p are 0.005 K and (26 × 10–6·p + 0.016 MPa), respectively.