Table 8. Experimental Speeds of Sound, w, for R1233zd(E) (trans-1-Chloro-3,3,3-trifluoroprop-1-ene), with the Combined Expanded (k = 2) Relative Uncertainty in the Speed of Sound, Uc, Given along with Relative Deviations from the Equation of State of Akasaka and Lemmon46a,b.
T (K) | P (MPa) | W (m·s–1) | Uc (k = 2) (%) | 100(w/wEOS – 1) |
---|---|---|---|---|
229.999 | 1.036 | 970.99 | 0.035 | –0.025 |
235.011 | 6.670 | 975.48 | 0.034 | –0.047 |
240.001 | 12.266 | 980.12 | 0.034 | –0.051 |
245.002 | 17.859 | 984.91 | 0.034 | –0.041 |
250.004 | 23.418 | 989.74 | 0.034 | –0.020 |
240.000 | 1.016 | 929.25 | 0.035 | –0.060 |
245.003 | 6.402 | 934.58 | 0.035 | –0.065 |
250.006 | 11.749 | 939.92 | 0.035 | –0.055 |
254.996 | 17.092 | 945.40 | 0.035 | –0.036 |
259.991 | 22.289 | 950.41 | 0.034 | –0.005 |
250.002 | 1.018 | 888.18 | 0.036 | –0.066 |
254.997 | 6.009 | 893.60 | 0.036 | –0.060 |
259.991 | 10.962 | 898.98 | 0.036 | –0.044 |
264.996 | 15.882 | 904.29 | 0.035 | –0.020 |
269.992 | 20.762 | 909.57 | 0.035 | 0.011 |
274.996 | 25.613 | 914.80 | 0.035 | 0.048 |
259.988 | 1.008 | 847.69 | 0.038 | –0.047 |
264.995 | 5.702 | 853.49 | 0.037 | –0.041 |
269.992 | 10.366 | 859.26 | 0.037 | –0.024 |
274.996 | 15.008 | 864.99 | 0.036 | –0.001 |
280.000 | 19.622 | 870.65 | 0.036 | 0.029 |
285.002 | 24.192 | 876.19 | 0.036 | 0.064 |
269.990 | 0.978 | 807.48 | 0.039 | –0.022 |
274.994 | 5.348 | 813.49 | 0.038 | –0.018 |
280.000 | 9.715 | 819.54 | 0.038 | –0.005 |
285.001 | 14.055 | 825.51 | 0.037 | 0.016 |
290.019 | 18.383 | 831.41 | 0.037 | 0.043 |
294.999 | 22.635 | 837.09 | 0.037 | 0.076 |
279.997 | 0.966 | 767.78 | 0.041 | 0.007 |
285.000 | 5.086 | 774.31 | 0.040 | 0.003 |
290.018 | 9.191 | 780.73 | 0.039 | 0.012 |
294.999 | 13.240 | 786.97 | 0.039 | 0.029 |
300.000 | 17.281 | 793.11 | 0.038 | 0.052 |
305.014 | 21.304 | 799.11 | 0.038 | 0.081 |
290.016 | 0.135 | 722.65 | 0.044 | 0.035 |
294.996 | 3.925 | 729.48 | 0.043 | 0.022 |
299.999 | 7.725 | 736.27 | 0.042 | 0.023 |
305.014 | 11.514 | 742.89 | 0.041 | 0.031 |
310.001 | 15.258 | 749.32 | 0.040 | 0.049 |
315.012 | 18.995 | 755.60 | 0.039 | 0.074 |
299.997 | 0.945 | 689.34 | 0.047 | 0.045 |
305.012 | 4.532 | 696.52 | 0.045 | 0.029 |
309.999 | 8.085 | 703.49 | 0.044 | 0.026 |
315.011 | 11.663 | 710.45 | 0.043 | 0.030 |
319.989 | 15.192 | 717.17 | 0.042 | 0.047 |
324.994 | 18.697 | 723.60 | 0.041 | 0.071 |
299.994 | 0.972 | 689.38 | 0.046 | 0.021 |
305.011 | 4.569 | 696.66 | 0.045 | 0.011 |
309.996 | 8.135 | 703.72 | 0.044 | 0.009 |
315.009 | 11.684 | 710.51 | 0.043 | 0.017 |
319.986 | 15.203 | 717.15 | 0.042 | 0.033 |
324.991 | 18.698 | 723.52 | 0.041 | 0.059 |
309.996 | 0.943 | 650.36 | 0.051 | 0.038 |
315.008 | 4.261 | 657.77 | 0.049 | 0.018 |
319.987 | 7.551 | 664.96 | 0.047 | 0.010 |
324.990 | 10.850 | 672.02 | 0.046 | 0.013 |
330.000 | 14.120 | 678.78 | 0.044 | 0.027 |
334.986 | 17.345 | 685.24 | 0.043 | 0.048 |
319.984 | 0.903 | 611.20 | 0.056 | 0.034 |
324.989 | 3.994 | 619.12 | 0.053 | 0.009 |
329.998 | 7.080 | 626.79 | 0.051 | –0.001 |
334.986 | 10.109 | 633.92 | 0.049 | 0.000 |
339.991 | 13.140 | 640.87 | 0.048 | 0.008 |
344.995 | 16.157 | 647.63 | 0.046 | 0.026 |
329.996 | 1.155 | 574.60 | 0.062 | 0.018 |
334.984 | 3.984 | 582.58 | 0.059 | –0.005 |
339.990 | 6.814 | 590.25 | 0.056 | –0.018 |
344.994 | 9.647 | 597.76 | 0.054 | –0.021 |
349.992 | 12.459 | 604.95 | 0.052 | –0.011 |
355.013 | 15.270 | 611.92 | 0.050 | 0.007 |
339.987 | 0.985 | 533.73 | 0.072 | –0.004 |
344.992 | 3.593 | 542.40 | 0.067 | 0.019 |
349.991 | 6.187 | 550.40 | 0.064 | 0.008 |
355.012 | 8.793 | 557.90 | 0.060 | –0.044 |
359.998 | 11.371 | 565.32 | 0.058 | –0.036 |
365.015 | 13.949 | 572.55 | 0.055 | –0.004 |
349.988 | 0.584 | 488.94 | 0.086 | –0.036 |
355.010 | 1.410 | 479.10 | 0.089 | –0.041 |
359.996 | 3.686 | 487.77 | 0.083 | –0.067 |
365.015 | 5.976 | 496.29 | 0.077 | –0.046 |
370.008 | 8.250 | 504.10 | 0.073 | –0.075 |
375.010 | 10.538 | 511.85 | 0.069 | –0.076 |
299.989 | 0.917 | 689.16 | 0.047 | 0.046 |
305.006 | 4.481 | 696.21 | 0.045 | 0.033 |
309.993 | 8.021 | 703.12 | 0.044 | 0.032 |
315.004 | 11.566 | 709.92 | 0.043 | 0.040 |
319.983 | 15.067 | 716.48 | 0.042 | 0.057 |
324.987 | 18.566 | 722.89 | 0.041 | 0.080 |
359.996 | 0.972 | 453.06 | 0.102 | –0.043 |
365.014 | 3.122 | 461.95 | 0.094 | –0.074 |
370.008 | 5.264 | 470.67 | 0.087 | –0.038 |
375.010 | 7.413 | 479.13 | 0.081 | 0.015 |
380.022 | 9.558 | 486.46 | 0.076 | –0.077 |
385.011 | 11.689 | 493.96 | 0.072 | –0.052 |
390.040 | 13.831 | 501.11 | 0.068 | –0.050 |
370.003 | 1.195 | 414.41 | 0.125 | –0.071 |
375.006 | 3.136 | 423.65 | 0.113 | –0.094 |
380.019 | 5.084 | 432.90 | 0.104 | –0.002 |
385.011 | 7.023 | 440.82 | 0.096 | –0.101 |
390.040 | 8.970 | 449.37 | 0.089 | 0.034 |
395.038 | 10.905 | 456.68 | 0.084 | –0.024 |
400.044 | 12.843 | 463.75 | 0.079 | –0.068 |
380.015 | 1.176 | 369.80 | 0.165 | –0.189 |
385.007 | 2.027 | 364.11 | 0.167 | –0.095 |
390.037 | 3.700 | 373.82 | 0.150 | –0.038 |
395.035 | 5.368 | 382.54 | 0.136 | –0.102 |
400.044 | 7.044 | 391.16 | 0.124 | –0.080 |
405.054 | 8.720 | 399.29 | 0.114 | –0.068 |
410.051 | 10.389 | 407.03 | 0.106 | –0.049 |
390.002 | 1.618 | 332.75 | 0.213 | –0.155 |
394.999 | 3.140 | 342.91 | 0.188 | –0.045 |
400.009 | 4.675 | 352.43 | 0.167 | 0.002 |
405.019 | 6.213 | 361.31 | 0.151 | 0.023 |
410.017 | 7.755 | 369.76 | 0.137 | 0.033 |
415.034 | 9.309 | 377.67 | 0.126 | –0.017 |
420.037 | 10.856 | 385.08 | 0.116 | –0.078 |
400.006 | 1.995 | 292.98 | 0.293 | –0.071 |
405.015 | 3.322 | 303.52 | 0.253 | 0.117 |
410.015 | 4.657 | 312.94 | 0.222 | 0.103 |
415.033 | 6.005 | 322.01 | 0.197 | 0.122 |
420.037 | 7.355 | 330.51 | 0.177 | 0.106 |
299.986 | 0.956 | 689.62 | 0.047 | 0.069 |
305.000 | 4.539 | 696.79 | 0.045 | 0.054 |
309.989 | 8.080 | 703.68 | 0.044 | 0.052 |
315.001 | 11.604 | 710.32 | 0.043 | 0.060 |
319.977 | 15.110 | 716.90 | 0.042 | 0.076 |
324.984 | 18.616 | 723.34 | 0.041 | 0.099 |
314.999 | 11.602 | 710.35 | 0.043 | 0.066 |
324.983 | 18.590 | 723.19 | 0.041 | 0.100 |
299.985 | 0.892 | 689.14 | 0.047 | 0.069 |
309.988 | 8.010 | 703.20 | 0.044 | 0.051 |
305.001 | 4.456 | 696.20 | 0.045 | 0.056 |
The listed data are averaged from 12 measured echo-delay times (4 sets of 3 replicates each); see Supporting Information for unaveraged data. The data are listed in the order measured; blank lines separate measured isochores.
The standard (k = 1) uncertainties in T and p are 0.005 K and (26 × 10–6p + 0.016 MPa), respectively.