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. 2023 Jul 28;62(31):12381–12406. doi: 10.1021/acs.iecr.3c01720

Table 9. Experimental Speeds of Sound, w, for R1336mzz(Z) (cis-1,1,1,4,4,4-Hexafluorobut-2-ene), with the Combined Expanded (k = 2) Relative Uncertainty in the Speed of Sound, Uc, Also Given along with Relative Deviations from the Equation of State of McLinden and Akasaka15a,b.

T (K) P (MPa) W (m·s–1) Uc (k = 2) (%) 100(w/wEOS – 1)
230.001 0.690 890.80 0.036 –0.033
235.011 6.133 895.90 0.035 –0.015
240.003 11.557 901.15 0.035 –0.006
245.011 16.982 906.51 0.035 0.000
250.008 22.349 911.84 0.035 0.005
255.000 27.667 917.13 0.034 0.009
259.991 32.983 922.55 0.034 0.013
264.998 38.176 927.57 0.034 0.019
       
245.008 1.010 832.01 0.037 –0.025
250.007 6.001 837.95 0.037 –0.020
254.997 10.946 843.83 0.036 –0.015
259.991 15.845 849.60 0.036 –0.011
264.998 20.691 855.19 0.036 –0.008
269.994 25.507 860.77 0.035 –0.007
274.997 30.284 866.25 0.035 –0.006
280.002 35.027 871.66 0.035 –0.005
285.003 39.722 876.95 0.035 –0.003
290.021 44.391 882.16 0.034 –0.001
         
259.987 0.901 773.45 0.039 –0.010
264.995 5.359 779.58 0.039 –0.010
269.993 9.820 785.85 0.038 –0.012
274.996 14.257 792.04 0.037 –0.012
280.002 18.657 798.09 0.037 –0.014
285.003 23.020 803.99 0.037 –0.017
290.022 27.366 809.81 0.036 –0.020
295.001 31.638 815.43 0.036 –0.024
300.003 35.903 821.00 0.036 –0.025
305.017 40.140 826.46 0.035 –0.025
310.003 44.320 831.80 0.035 –0.022
       
274.993 0.674 715.73 0.042 0.001
279.998 4.721 722.55 0.041 –0.003
285.001 8.744 729.24 0.040 –0.005
290.019 12.752 735.79 0.040 –0.010
294.999 16.677 741.98 0.039 –0.018
300.001 20.612 748.17 0.038 –0.025
305.016 24.544 754.28 0.038 –0.032
310.003 28.423 760.22 0.037 –0.038
315.015 32.292 766.05 0.037 –0.040
319.991 36.101 771.69 0.037 –0.042
324.996 39.899 777.24 0.036 –0.040
330.003 43.670 782.67 0.036 –0.035
       
290.015 0.889 662.22 0.046 0.008
294.995 4.513 669.38 0.044 0.004
299.998 8.136 676.40 0.043 –0.002
305.013 11.751 683.25 0.042 –0.010
309.999 15.324 689.89 0.042 –0.020
315.013 18.901 696.42 0.041 –0.028
319.990 22.419 702.67 0.040 –0.036
324.996 25.937 708.82 0.039 –0.042
330.003 29.430 714.81 0.039 –0.046
334.988 32.848 720.44 0.038 –0.048
339.993 36.281 726.10 0.038 –0.048
       
290.013 0.799 661.60 0.046 0.009
294.994 4.420 668.78 0.044 0.007
299.996 8.044 675.82 0.043 –0.001
305.011 11.658 682.70 0.042 –0.009
309.998 15.228 689.33 0.042 –0.019
315.010 18.798 695.84 0.041 –0.027
319.988 22.316 702.11 0.040 –0.035
324.994 25.829 708.26 0.039 –0.041
330.001 29.322 714.26 0.039 –0.045
334.988 32.737 719.89 0.038 –0.047
339.994 36.162 725.52 0.038 –0.047
344.998 39.569 731.06 0.037 –0.046
349.994 42.948 736.46 0.037 –0.043
       
305.008 0.774 607.69 0.051 0.010
309.995 4.014 615.20 0.049 0.009
315.008 7.255 622.52 0.048 0.005
319.985 10.473 629.65 0.046 –0.004
324.990 13.691 636.60 0.045 –0.014
329.999 16.885 643.29 0.044 –0.022
334.986 20.007 649.50 0.043 –0.032
339.992 23.149 655.74 0.042 –0.039
344.997 26.279 661.86 0.041 –0.045
349.994 29.390 667.84 0.041 –0.048
355.016 32.494 673.69 0.040 –0.049
360.000 35.557 679.36 0.040 –0.049
365.018 38.617 684.91 0.039 –0.047
370.011 41.647 690.34 0.039 –0.042
375.013 44.656 695.63 0.038 –0.036
       
319.980 0.866 555.63 0.059 0.019
324.986 3.756 563.45 0.056 0.024
329.995 6.644 571.05 0.054 0.023
334.982 9.488 578.17 0.052 0.013
339.988 12.349 585.23 0.050 0.003
344.993 15.196 592.07 0.049 –0.008
349.991 18.022 598.66 0.047 –0.017
355.012 20.849 605.11 0.046 –0.026
359.998 23.645 611.36 0.045 –0.032
365.016 26.444 617.48 0.044 –0.036
370.010 29.215 623.42 0.043 –0.037
375.013 31.980 629.24 0.042 –0.037
380.024 34.723 634.88 0.042 –0.034
385.014 37.440 640.35 0.041 –0.032
390.043 40.164 645.76 0.040 –0.027
395.040 42.854 651.01 0.040 –0.021
400.047 45.534 656.16 0.039 –0.014
       
334.976 0.903 503.45 0.070 0.027
339.983 3.459 511.60 0.066 0.038
344.988 6.011 519.44 0.063 0.039
349.986 8.552 526.97 0.060 0.033
355.008 11.097 534.26 0.058 0.024
359.994 13.616 541.26 0.055 0.014
365.012 16.141 548.06 0.053 0.003
370.006 18.645 554.63 0.052 –0.006
375.009 21.136 560.96 0.050 –0.013
380.021 23.625 567.27 0.049 –0.002
385.012 26.090 573.17 0.048 –0.021
390.041 28.574 579.14 0.046 –0.020
395.039 31.008 584.79 0.045 –0.017
400.047 33.444 590.36 0.045 –0.014
405.055 35.871 595.83 0.044 –0.008
410.053 38.283 601.17 0.043 –0.002
415.070 40.695 606.44 0.042 0.006
420.073 43.086 611.57 0.042 0.016
       
290.007 0.841 662.08 0.046 0.033
294.988 4.444 669.12 0.044 0.031
299.990 8.064 676.14 0.043 0.025
305.006 11.675 682.99 0.042 0.017
309.992 15.247 689.63 0.042 0.007
315.004 18.819 696.16 0.041 –0.002
319.982 22.342 702.45 0.040 –0.010
324.986 25.860 708.61 0.039 –0.016
329.994 29.353 714.61 0.039 –0.020
334.982 32.769 720.24 0.038 –0.023
339.986 36.195 725.86 0.038 –0.024
344.991 39.587 731.33 0.037 –0.022
349.989 42.900 736.44 0.037 –0.018
       
349.988 0.989 451.60 0.087 0.021
355.010 3.232 460.37 0.081 0.104
359.995 5.457 468.15 0.076 0.055
365.013 7.692 476.00 0.072 0.079
370.006 9.916 483.41 0.068 0.068
375.009 12.137 490.42 0.065 0.029
380.020 14.355 497.39 0.062 0.032
385.011 16.553 504.08 0.060 0.039
390.040 18.764 510.43 0.058 0.005
395.038 20.952 517.16 0.056 0.095
400.045 23.136 523.02 0.054 0.050
405.054 25.316 528.73 0.052 0.005
410.052 27.482 534.50 0.051 0.006
415.070 29.651 540.09 0.050 –0.007
420.072 31.808 545.71 0.048 0.014
       
365.004 0.867 396.29 0.116 0.029
369.999 2.778 404.95 0.107 0.042
375.002 4.698 413.34 0.099 0.066
380.015 6.619 421.23 0.092 0.054
385.006 8.531 428.90 0.086 0.072
390.036 10.453 435.85 0.081 –0.014
395.034 12.362 443.06 0.077 0.028
400.042 14.273 449.83 0.073 0.020
405.052 16.182 456.57 0.069 0.056
410.050 18.083 462.79 0.067 0.027
415.069 19.987 468.91 0.064 0.013
420.072 21.883 475.13 0.061 0.060
       
380.013 1.047 343.10 0.162 0.006
385.005 2.664 352.08 0.146 0.040
390.034 4.300 360.80 0.133 0.092
395.033 5.930 368.75 0.122 0.053
400.041 7.565 376.40 0.113 0.025
405.051 9.202 383.58 0.105 –0.039
410.050 10.838 390.90 0.098 0.010
415.068 12.483 397.86 0.092 0.020
420.072 14.116 404.49 0.087 0.033
       
394.998 1.269 288.13 0.250 0.072
400.007 2.607 297.47 0.219 0.100
405.017 3.953 306.20 0.194 0.092
410.016 5.305 314.36 0.174 0.043
415.035 6.669 322.32 0.158 0.047
420.038 8.032 329.88 0.144 0.052
       
290.006 0.858 662.20 0.046 0.033
294.988 4.472 669.31 0.044 0.031
299.989 8.097 676.34 0.043 0.022
305.004 11.707 683.18 0.042 0.014
309.991 15.254 689.68 0.041 0.007
315.003 18.816 696.14 0.041 –0.001
319.981 22.331 702.40 0.040 –0.008
324.986 25.839 708.51 0.039 –0.015
329.993 29.326 714.48 0.039 –0.020
334.980 32.736 720.08 0.038 –0.023
339.986 36.158 725.69 0.038 –0.024
344.990 39.534 731.08 0.037 –0.021
349.987 42.803 735.99 0.037 –0.017
a

The listed data are averaged from 12 measured echo-delay times (4 sets of 3 replicates each); see Supporting Information for unaveraged data. The data are listed in the order measured; blank lines separate measured isochores.

b

The standard (k = 1) uncertainties in T and p are 0.005 K and (26 × 10–6p + 0.016 MPa), respectively.