Table 9. Experimental Speeds of Sound, w, for R1336mzz(Z) (cis-1,1,1,4,4,4-Hexafluorobut-2-ene), with the Combined Expanded (k = 2) Relative Uncertainty in the Speed of Sound, Uc, Also Given along with Relative Deviations from the Equation of State of McLinden and Akasaka15a,b.
T (K) | P (MPa) | W (m·s–1) | Uc (k = 2) (%) | 100(w/wEOS – 1) |
---|---|---|---|---|
230.001 | 0.690 | 890.80 | 0.036 | –0.033 |
235.011 | 6.133 | 895.90 | 0.035 | –0.015 |
240.003 | 11.557 | 901.15 | 0.035 | –0.006 |
245.011 | 16.982 | 906.51 | 0.035 | 0.000 |
250.008 | 22.349 | 911.84 | 0.035 | 0.005 |
255.000 | 27.667 | 917.13 | 0.034 | 0.009 |
259.991 | 32.983 | 922.55 | 0.034 | 0.013 |
264.998 | 38.176 | 927.57 | 0.034 | 0.019 |
245.008 | 1.010 | 832.01 | 0.037 | –0.025 |
250.007 | 6.001 | 837.95 | 0.037 | –0.020 |
254.997 | 10.946 | 843.83 | 0.036 | –0.015 |
259.991 | 15.845 | 849.60 | 0.036 | –0.011 |
264.998 | 20.691 | 855.19 | 0.036 | –0.008 |
269.994 | 25.507 | 860.77 | 0.035 | –0.007 |
274.997 | 30.284 | 866.25 | 0.035 | –0.006 |
280.002 | 35.027 | 871.66 | 0.035 | –0.005 |
285.003 | 39.722 | 876.95 | 0.035 | –0.003 |
290.021 | 44.391 | 882.16 | 0.034 | –0.001 |
259.987 | 0.901 | 773.45 | 0.039 | –0.010 |
264.995 | 5.359 | 779.58 | 0.039 | –0.010 |
269.993 | 9.820 | 785.85 | 0.038 | –0.012 |
274.996 | 14.257 | 792.04 | 0.037 | –0.012 |
280.002 | 18.657 | 798.09 | 0.037 | –0.014 |
285.003 | 23.020 | 803.99 | 0.037 | –0.017 |
290.022 | 27.366 | 809.81 | 0.036 | –0.020 |
295.001 | 31.638 | 815.43 | 0.036 | –0.024 |
300.003 | 35.903 | 821.00 | 0.036 | –0.025 |
305.017 | 40.140 | 826.46 | 0.035 | –0.025 |
310.003 | 44.320 | 831.80 | 0.035 | –0.022 |
274.993 | 0.674 | 715.73 | 0.042 | 0.001 |
279.998 | 4.721 | 722.55 | 0.041 | –0.003 |
285.001 | 8.744 | 729.24 | 0.040 | –0.005 |
290.019 | 12.752 | 735.79 | 0.040 | –0.010 |
294.999 | 16.677 | 741.98 | 0.039 | –0.018 |
300.001 | 20.612 | 748.17 | 0.038 | –0.025 |
305.016 | 24.544 | 754.28 | 0.038 | –0.032 |
310.003 | 28.423 | 760.22 | 0.037 | –0.038 |
315.015 | 32.292 | 766.05 | 0.037 | –0.040 |
319.991 | 36.101 | 771.69 | 0.037 | –0.042 |
324.996 | 39.899 | 777.24 | 0.036 | –0.040 |
330.003 | 43.670 | 782.67 | 0.036 | –0.035 |
290.015 | 0.889 | 662.22 | 0.046 | 0.008 |
294.995 | 4.513 | 669.38 | 0.044 | 0.004 |
299.998 | 8.136 | 676.40 | 0.043 | –0.002 |
305.013 | 11.751 | 683.25 | 0.042 | –0.010 |
309.999 | 15.324 | 689.89 | 0.042 | –0.020 |
315.013 | 18.901 | 696.42 | 0.041 | –0.028 |
319.990 | 22.419 | 702.67 | 0.040 | –0.036 |
324.996 | 25.937 | 708.82 | 0.039 | –0.042 |
330.003 | 29.430 | 714.81 | 0.039 | –0.046 |
334.988 | 32.848 | 720.44 | 0.038 | –0.048 |
339.993 | 36.281 | 726.10 | 0.038 | –0.048 |
290.013 | 0.799 | 661.60 | 0.046 | 0.009 |
294.994 | 4.420 | 668.78 | 0.044 | 0.007 |
299.996 | 8.044 | 675.82 | 0.043 | –0.001 |
305.011 | 11.658 | 682.70 | 0.042 | –0.009 |
309.998 | 15.228 | 689.33 | 0.042 | –0.019 |
315.010 | 18.798 | 695.84 | 0.041 | –0.027 |
319.988 | 22.316 | 702.11 | 0.040 | –0.035 |
324.994 | 25.829 | 708.26 | 0.039 | –0.041 |
330.001 | 29.322 | 714.26 | 0.039 | –0.045 |
334.988 | 32.737 | 719.89 | 0.038 | –0.047 |
339.994 | 36.162 | 725.52 | 0.038 | –0.047 |
344.998 | 39.569 | 731.06 | 0.037 | –0.046 |
349.994 | 42.948 | 736.46 | 0.037 | –0.043 |
305.008 | 0.774 | 607.69 | 0.051 | 0.010 |
309.995 | 4.014 | 615.20 | 0.049 | 0.009 |
315.008 | 7.255 | 622.52 | 0.048 | 0.005 |
319.985 | 10.473 | 629.65 | 0.046 | –0.004 |
324.990 | 13.691 | 636.60 | 0.045 | –0.014 |
329.999 | 16.885 | 643.29 | 0.044 | –0.022 |
334.986 | 20.007 | 649.50 | 0.043 | –0.032 |
339.992 | 23.149 | 655.74 | 0.042 | –0.039 |
344.997 | 26.279 | 661.86 | 0.041 | –0.045 |
349.994 | 29.390 | 667.84 | 0.041 | –0.048 |
355.016 | 32.494 | 673.69 | 0.040 | –0.049 |
360.000 | 35.557 | 679.36 | 0.040 | –0.049 |
365.018 | 38.617 | 684.91 | 0.039 | –0.047 |
370.011 | 41.647 | 690.34 | 0.039 | –0.042 |
375.013 | 44.656 | 695.63 | 0.038 | –0.036 |
319.980 | 0.866 | 555.63 | 0.059 | 0.019 |
324.986 | 3.756 | 563.45 | 0.056 | 0.024 |
329.995 | 6.644 | 571.05 | 0.054 | 0.023 |
334.982 | 9.488 | 578.17 | 0.052 | 0.013 |
339.988 | 12.349 | 585.23 | 0.050 | 0.003 |
344.993 | 15.196 | 592.07 | 0.049 | –0.008 |
349.991 | 18.022 | 598.66 | 0.047 | –0.017 |
355.012 | 20.849 | 605.11 | 0.046 | –0.026 |
359.998 | 23.645 | 611.36 | 0.045 | –0.032 |
365.016 | 26.444 | 617.48 | 0.044 | –0.036 |
370.010 | 29.215 | 623.42 | 0.043 | –0.037 |
375.013 | 31.980 | 629.24 | 0.042 | –0.037 |
380.024 | 34.723 | 634.88 | 0.042 | –0.034 |
385.014 | 37.440 | 640.35 | 0.041 | –0.032 |
390.043 | 40.164 | 645.76 | 0.040 | –0.027 |
395.040 | 42.854 | 651.01 | 0.040 | –0.021 |
400.047 | 45.534 | 656.16 | 0.039 | –0.014 |
334.976 | 0.903 | 503.45 | 0.070 | 0.027 |
339.983 | 3.459 | 511.60 | 0.066 | 0.038 |
344.988 | 6.011 | 519.44 | 0.063 | 0.039 |
349.986 | 8.552 | 526.97 | 0.060 | 0.033 |
355.008 | 11.097 | 534.26 | 0.058 | 0.024 |
359.994 | 13.616 | 541.26 | 0.055 | 0.014 |
365.012 | 16.141 | 548.06 | 0.053 | 0.003 |
370.006 | 18.645 | 554.63 | 0.052 | –0.006 |
375.009 | 21.136 | 560.96 | 0.050 | –0.013 |
380.021 | 23.625 | 567.27 | 0.049 | –0.002 |
385.012 | 26.090 | 573.17 | 0.048 | –0.021 |
390.041 | 28.574 | 579.14 | 0.046 | –0.020 |
395.039 | 31.008 | 584.79 | 0.045 | –0.017 |
400.047 | 33.444 | 590.36 | 0.045 | –0.014 |
405.055 | 35.871 | 595.83 | 0.044 | –0.008 |
410.053 | 38.283 | 601.17 | 0.043 | –0.002 |
415.070 | 40.695 | 606.44 | 0.042 | 0.006 |
420.073 | 43.086 | 611.57 | 0.042 | 0.016 |
290.007 | 0.841 | 662.08 | 0.046 | 0.033 |
294.988 | 4.444 | 669.12 | 0.044 | 0.031 |
299.990 | 8.064 | 676.14 | 0.043 | 0.025 |
305.006 | 11.675 | 682.99 | 0.042 | 0.017 |
309.992 | 15.247 | 689.63 | 0.042 | 0.007 |
315.004 | 18.819 | 696.16 | 0.041 | –0.002 |
319.982 | 22.342 | 702.45 | 0.040 | –0.010 |
324.986 | 25.860 | 708.61 | 0.039 | –0.016 |
329.994 | 29.353 | 714.61 | 0.039 | –0.020 |
334.982 | 32.769 | 720.24 | 0.038 | –0.023 |
339.986 | 36.195 | 725.86 | 0.038 | –0.024 |
344.991 | 39.587 | 731.33 | 0.037 | –0.022 |
349.989 | 42.900 | 736.44 | 0.037 | –0.018 |
349.988 | 0.989 | 451.60 | 0.087 | 0.021 |
355.010 | 3.232 | 460.37 | 0.081 | 0.104 |
359.995 | 5.457 | 468.15 | 0.076 | 0.055 |
365.013 | 7.692 | 476.00 | 0.072 | 0.079 |
370.006 | 9.916 | 483.41 | 0.068 | 0.068 |
375.009 | 12.137 | 490.42 | 0.065 | 0.029 |
380.020 | 14.355 | 497.39 | 0.062 | 0.032 |
385.011 | 16.553 | 504.08 | 0.060 | 0.039 |
390.040 | 18.764 | 510.43 | 0.058 | 0.005 |
395.038 | 20.952 | 517.16 | 0.056 | 0.095 |
400.045 | 23.136 | 523.02 | 0.054 | 0.050 |
405.054 | 25.316 | 528.73 | 0.052 | 0.005 |
410.052 | 27.482 | 534.50 | 0.051 | 0.006 |
415.070 | 29.651 | 540.09 | 0.050 | –0.007 |
420.072 | 31.808 | 545.71 | 0.048 | 0.014 |
365.004 | 0.867 | 396.29 | 0.116 | 0.029 |
369.999 | 2.778 | 404.95 | 0.107 | 0.042 |
375.002 | 4.698 | 413.34 | 0.099 | 0.066 |
380.015 | 6.619 | 421.23 | 0.092 | 0.054 |
385.006 | 8.531 | 428.90 | 0.086 | 0.072 |
390.036 | 10.453 | 435.85 | 0.081 | –0.014 |
395.034 | 12.362 | 443.06 | 0.077 | 0.028 |
400.042 | 14.273 | 449.83 | 0.073 | 0.020 |
405.052 | 16.182 | 456.57 | 0.069 | 0.056 |
410.050 | 18.083 | 462.79 | 0.067 | 0.027 |
415.069 | 19.987 | 468.91 | 0.064 | 0.013 |
420.072 | 21.883 | 475.13 | 0.061 | 0.060 |
380.013 | 1.047 | 343.10 | 0.162 | 0.006 |
385.005 | 2.664 | 352.08 | 0.146 | 0.040 |
390.034 | 4.300 | 360.80 | 0.133 | 0.092 |
395.033 | 5.930 | 368.75 | 0.122 | 0.053 |
400.041 | 7.565 | 376.40 | 0.113 | 0.025 |
405.051 | 9.202 | 383.58 | 0.105 | –0.039 |
410.050 | 10.838 | 390.90 | 0.098 | 0.010 |
415.068 | 12.483 | 397.86 | 0.092 | 0.020 |
420.072 | 14.116 | 404.49 | 0.087 | 0.033 |
394.998 | 1.269 | 288.13 | 0.250 | 0.072 |
400.007 | 2.607 | 297.47 | 0.219 | 0.100 |
405.017 | 3.953 | 306.20 | 0.194 | 0.092 |
410.016 | 5.305 | 314.36 | 0.174 | 0.043 |
415.035 | 6.669 | 322.32 | 0.158 | 0.047 |
420.038 | 8.032 | 329.88 | 0.144 | 0.052 |
290.006 | 0.858 | 662.20 | 0.046 | 0.033 |
294.988 | 4.472 | 669.31 | 0.044 | 0.031 |
299.989 | 8.097 | 676.34 | 0.043 | 0.022 |
305.004 | 11.707 | 683.18 | 0.042 | 0.014 |
309.991 | 15.254 | 689.68 | 0.041 | 0.007 |
315.003 | 18.816 | 696.14 | 0.041 | –0.001 |
319.981 | 22.331 | 702.40 | 0.040 | –0.008 |
324.986 | 25.839 | 708.51 | 0.039 | –0.015 |
329.993 | 29.326 | 714.48 | 0.039 | –0.020 |
334.980 | 32.736 | 720.08 | 0.038 | –0.023 |
339.986 | 36.158 | 725.69 | 0.038 | –0.024 |
344.990 | 39.534 | 731.08 | 0.037 | –0.021 |
349.987 | 42.803 | 735.99 | 0.037 | –0.017 |
The listed data are averaged from 12 measured echo-delay times (4 sets of 3 replicates each); see Supporting Information for unaveraged data. The data are listed in the order measured; blank lines separate measured isochores.
The standard (k = 1) uncertainties in T and p are 0.005 K and (26 × 10–6p + 0.016 MPa), respectively.