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. 2023 Jul 11;123(15):9653–9675. doi: 10.1021/acs.chemrev.3c00217

Scheme 12. Proposed Mechanism for the C–C Bond Formation between a Diarylester and Phenylacetylene Using the PMes3/B(C6F5)3 FLP: (A) Formation of the Diaryl Carbocation; (B) Radical Pathway Leading to the Product; (C) Diamagnetic Pathway Leading to the Cross-Coupled Product.

Scheme 12