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. 2023 Aug 2;12(8):1173–1178. doi: 10.1021/acsmacrolett.3c00389

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© 2023 The Authors. Published by American Chemical Society

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(A) Change of color of a solution of CuCl₂/TPMA upon heating at 135 and 175 °C in propylene carbonate. (B) UV–vis spectra of CuCl₂ and CuCl₂/TPMA (0.016 M) under different conditions. (C) DSC thermogram of CuCl₂/TPMA complex. (D) Classical ATRP mechanism using CuCl/TPMA (a), ARGET ATRP (b), and the postulated depolymerization mechanism (c).