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. Author manuscript; available in PMC: 2023 Aug 17.
Published in final edited form as: Org Lett. 2022 Jul 11;24(28):5176–5180. doi: 10.1021/acs.orglett.2c02012

Scheme 2.

Scheme 2.

Synthetic Scheme for the Late-Stage modification of Atosiban (A) and Cyclo-RGDf (B) Peptides for Photochemical Homologation and Cyclizations

Concentrations and equivalents are based on resin loading. a Conversion determined by acylation and crude HPLC. b Crude HPLC yields are reported and obtained by standard curves based on quantitative 1H NMR. c Isolated yields reported.