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. 2023 Aug 18;13(35):24731–24754. doi: 10.1039/d3ra03472k

Details of chitosan-based hydrogels.

Polymer Synthesis method & cross-linker used Swelling degree (SD)/water absorption Agricultural application Reference
Chitosan, poly(acrylic acid-co-acrylamide) Spray coating followed by chemical cross-linking (N,N-methylene-bis-acrylamide-cross linker) 40–70 g g−1 in distilled water Enhance water retention, controlled release of fertilizer 24
Chitosan Chemical cross-linking (genipin-cross linker) 112–145% in distilled water Increased water uptake by the plant, controlled release of urea 25
Chitosan Chemical cross-linking (glyoxal-cross linker) Slow release of agrochemicals (dicyandiamide/DCD) 26
Chitosan, polyvinyl alcohol, acrylamide, and acrylic acid Reverse suspension polymerization (chemical cross-linking) (glutaraldehyde and N,N-methylene-bis-acrylamide-cross linker) 120–230 g g−1 in deionized water Enhance water absorption capacity of the soil, controlled fertilizer release 27
Chitosan Chemical cross-linking (EDTA–urea-cross linker) 238–570 g g−1 in distilled water Water absorption, controlled release of urea and metal ions 28
Chitosan and high acetyl gellan gum (HAGG) Cross-linking via ionic bond formation 219 g g−1 in pure water Water retention, controlled release of fertilizer 29
Chitosan, silk fibroin and gelatin Blended hydrogel (no intermolecular interaction) 5.32 parts per hundred of polymer Slow release of urea 30
Chitosan–cellulose and acrylic acid Graft polymerization 390 g g−1 in distilled water and 39.5 g g−1 in saline solution (0.9% NaCl) Increase water absorption capacity of soil 31
Controlled release of fertilizer
Chitosan and starch Inotropic gelation technique Controlled release of agrochemicals 32
Chitosan, sodium alginate, and polyacrylamide Radiation-induced polymerization (gamma-radiations) 397 g g−1 in distilled water (maximum absorption) Water retention, soil conditioning, increase plant growth 33
Chitosan, poly(acrylic acid-co-acrylamide (ground basalt for making composite) Graft free radical co-polymerization ∼600 g g−1 at pH = 3 Soil conditioning enhances plant growth and pH-sensitive water absorption 34
Chitosan and polyvinyl alcohol Freeze thawing method 58.3% in distilled water (with 6 wt% chitosan) Water retention, increased plant germination, and controlled release of fertilizer 35
Chitosan Graft polymerization and mild oxidation ∼2500% in distilled water Water regulation, controlled urea release 36
Chitosan and starch Ionotropic gelation and neutralization 143–235% in distilled water Water retention, bio-fertilizer 37
Chitosan Chemical cross-linking (citric acid-cross linker) 1250 g g−1 in distilled water Water absorption 38
Chitosan Chemical cross-linking salicylaldehyde-cross linker) 154% in distilled water Water absorption, controlled fertilizer release, enhanced plant growth 39
Chitosan, gelatin and PVA Chemical cross-linking 10–12 times than its mass Controlled delivery of agrochemical (inulin), water absorption 40
Chitosan ad starch Chemical cross-linking (glycerol & citric acid-cross linker) Biodegradable mulch for invasive plants increases plant growth 41
Chitosan and starch Ionotropic gelation 120–162% in distilled water Controlled release of fertilizer, water absorption 42
Chitosan-co-polyacrylamide–TiO2 Chemical cross-linking (glutaraldehyde-cross linker) 364.76% without TiO2 maximum swelling Soil conditioner, plant growth promoter 43
66.45–100% in distilled water
Chitosan and starch Chemical cross-linking (citric acid-cross linker) ∼120% (almost the same in distilled water, glucose solution, and urea) Increase water absorption capacity of soil 44