Fig. 2. The structure of gigantic {Mo₁₃₂} capped wheel.

Polyhedral and ball-and-stick representations of a {Mo₁₁₀} wheel, b the angle of capping moieties, c 1a, d the cavity (shown gray) in 1a, e–g two types of edge-sharing {Mo₂} units, h side view of 1a and i anisotropic ligand distributions in 1a. Color code: Mo blue/red/cyan/yellow, S orange, O gray, C pink.