| Ni1—N1i | 1.9168 (19) | C7—H7B | 0.9900 |
| Ni1—N1 | 1.9168 (19) | C8—C9 | 1.521 (3) |
| Ni1—S1i | 2.1735 (7) | C8—H8A | 0.9900 |
| Ni1—S1i | 2.1735 (7) | C8—H8B | 0.9900 |
| Ni1—S1 | 2.1735 (7) | C9—C10 | 1.519 (3) |
| S1—C6 | 1.717 (2) | C9—H9A | 0.9900 |
| S2—C6 | 1.745 (2) | C9—H9B | 0.9900 |
| S2—C7 | 1.809 (2) | C10—C11 | 1.520 (3) |
| S3—C1 | 1.709 (3) | C10—H10A | 0.9900 |
| S3—C4 | 1.725 (3) | C10—H10B | 0.9900 |
| N1—C5 | 1.304 (3) | C11—C12 | 1.516 (4) |
| N1—N2 | 1.404 (3) | C11—H11A | 0.9900 |
| N2—C6 | 1.298 (3) | C11—H11B | 0.9900 |
| C1—C2 | 1.351 (4) | C12—C13 | 1.515 (4) |
| C1—H1 | 0.9500 | C12—H12A | 0.9900 |
| C2—C3 | 1.402 (4) | C12—H12B | 0.9900 |
| C2—H2 | 0.9500 | C13—C14 | 1.513 (4) |
| C3—C4 | 1.386 (3) | C13—H13A | 0.9900 |
| C3—H3 | 0.9500 | C13—H13B | 0.9900 |
| C4—C5 | 1.431 (3) | C14—H14A | 0.9800 |
| C5—H5 | 0.9500 | C14—H14B | 0.9800 |
| C7—C8 | 1.524 (3) | C14—H14C | 0.9800 |
| C7—H7A | 0.9900 | ||
| N1i—Ni1—N1 | 180.0 | C9—C8—H8A | 109.8 |
| N1i—Ni1—S1i | 85.88 (6) | C7—C8—H8A | 109.8 |
| N1—Ni1—S1i | 94.12 (6) | C9—C8—H8B | 109.8 |
| N1i—Ni1—S1i | 85.88 (6) | C7—C8—H8B | 109.8 |
| N1—Ni1—S1i | 94.12 (6) | H8A—C8—H8B | 108.3 |
| S1i—Ni1—S1i | 0.00 (2) | C10—C9—C8 | 114.7 (2) |
| N1i—Ni1—S1 | 94.12 (6) | C10—C9—H9A | 108.6 |
| N1—Ni1—S1 | 85.88 (6) | C8—C9—H9A | 108.6 |
| S1i—Ni1—S1 | 180.0 | C10—C9—H9B | 108.6 |
| S1i—Ni1—S1 | 180.0 | C8—C9—H9B | 108.6 |
| C6—S1—Ni1 | 96.42 (8) | H9A—C9—H9B | 107.6 |
| C6—S2—C7 | 100.88 (12) | C9—C10—C11 | 112.4 (2) |
| C1—S3—C4 | 91.32 (13) | C9—C10—H10A | 109.1 |
| C5—N1—N2 | 111.8 (2) | C11—C10—H10A | 109.1 |
| C5—N1—Ni1 | 126.77 (17) | C9—C10—H10B | 109.1 |
| N2—N1—Ni1 | 121.46 (14) | C11—C10—H10B | 109.1 |
| C6—N2—N1 | 111.74 (19) | H10A—C10—H10B | 107.9 |
| C2—C1—S3 | 112.9 (2) | C12—C11—C10 | 114.6 (2) |
| C2—C1—H1 | 123.6 | C12—C11—H11A | 108.6 |
| S3—C1—H1 | 123.6 | C10—C11—H11A | 108.6 |
| C1—C2—C3 | 112.4 (2) | C12—C11—H11B | 108.6 |
| C1—C2—H2 | 123.8 | C10—C11—H11B | 108.6 |
| C3—C2—H2 | 123.8 | H11A—C11—H11B | 107.6 |
| C4—C3—C2 | 112.9 (2) | C13—C12—C11 | 113.4 (2) |
| C4—C3—H3 | 123.5 | C13—C12—H12A | 108.9 |
| C2—C3—H3 | 123.5 | C11—C12—H12A | 108.9 |
| C3—C4—C5 | 122.6 (2) | C13—C12—H12B | 108.9 |
| C3—C4—S3 | 110.53 (18) | C11—C12—H12B | 108.9 |
| C5—C4—S3 | 126.78 (19) | H12A—C12—H12B | 107.7 |
| N1—C5—C4 | 130.1 (2) | C14—C13—C12 | 113.7 (3) |
| N1—C5—H5 | 115.0 | C14—C13—H13A | 108.8 |
| C4—C5—H5 | 115.0 | C12—C13—H13A | 108.8 |
| N2—C6—S1 | 124.49 (19) | C14—C13—H13B | 108.8 |
| N2—C6—S2 | 119.99 (18) | C12—C13—H13B | 108.8 |
| S1—C6—S2 | 115.51 (14) | H13A—C13—H13B | 107.7 |
| C8—C7—S2 | 111.63 (17) | C13—C14—H14A | 109.5 |
| C8—C7—H7A | 109.3 | C13—C14—H14B | 109.5 |
| S2—C7—H7A | 109.3 | H14A—C14—H14B | 109.5 |
| C8—C7—H7B | 109.3 | C13—C14—H14C | 109.5 |
| S2—C7—H7B | 109.3 | H14A—C14—H14C | 109.5 |
| H7A—C7—H7B | 108.0 | H14B—C14—H14C | 109.5 |
| C9—C8—C7 | 109.2 (2) | ||
| C5—N1—N2—C6 | −179.6 (2) | N1—N2—C6—S1 | −1.3 (3) |
| Ni1—N1—N2—C6 | 0.4 (3) | N1—N2—C6—S2 | 177.52 (15) |
| C4—S3—C1—C2 | −1.0 (2) | Ni1—S1—C6—N2 | 1.4 (2) |
| S3—C1—C2—C3 | 0.9 (3) | Ni1—S1—C6—S2 | −177.45 (11) |
| C1—C2—C3—C4 | −0.3 (3) | C7—S2—C6—N2 | 2.3 (2) |
| C2—C3—C4—C5 | 176.5 (2) | C7—S2—C6—S1 | −178.84 (14) |
| C2—C3—C4—S3 | −0.5 (3) | C6—S2—C7—C8 | −177.36 (18) |
| C1—S3—C4—C3 | 0.8 (2) | S2—C7—C8—C9 | 178.55 (18) |
| C1—S3—C4—C5 | −176.0 (2) | C7—C8—C9—C10 | −177.8 (2) |
| N2—N1—C5—C4 | −2.1 (4) | C8—C9—C10—C11 | 176.7 (2) |
| Ni1—N1—C5—C4 | 177.9 (2) | C9—C10—C11—C12 | −179.8 (2) |
| C3—C4—C5—N1 | 178.5 (3) | C10—C11—C12—C13 | 178.0 (3) |
| S3—C4—C5—N1 | −5.1 (4) | C11—C12—C13—C14 | 179.1 (3) |