Crystal-structure determination and Hirshfeld surface analysis of two new thio­phene derivatives: (E)-N-{2-[2-(benzo[b]thio­phen-2-yl)ethen­yl]-5-fluoro­phen­yl}benzene­sulfonamide and (E)-N-{2-[2-(benzo[b]thio­phen-2-yl)ethen­yl]-5-fluoro­phen­yl}-N-(but-2-yn-1-yl)benzene­sulfonamide

. 2023 Jul 21;79(Pt 8):741–746. doi: 10.1107/S2056989023006096

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.060 (3)	0.078 (3)	0.063 (3)	−0.003 (2)	0.026 (2)	−0.005 (2)
C2	0.073 (3)	0.097 (4)	0.066 (3)	−0.005 (3)	0.033 (3)	0.000 (3)
C3	0.080 (4)	0.107 (4)	0.059 (3)	0.005 (3)	0.029 (3)	−0.003 (3)
C4	0.074 (3)	0.089 (3)	0.062 (3)	0.001 (3)	0.025 (3)	−0.013 (2)
C5	0.063 (3)	0.079 (3)	0.066 (3)	−0.008 (2)	0.019 (2)	−0.013 (2)
C6	0.060 (3)	0.071 (3)	0.056 (2)	−0.001 (2)	0.024 (2)	−0.008 (2)
C7	0.065 (3)	0.072 (3)	0.065 (3)	−0.015 (2)	0.028 (2)	−0.005 (2)
C8	0.063 (3)	0.064 (2)	0.057 (2)	−0.005 (2)	0.027 (2)	−0.003 (2)
C9	0.068 (3)	0.071 (3)	0.061 (3)	−0.007 (2)	0.023 (2)	−0.004 (2)
C10	0.064 (3)	0.065 (3)	0.059 (2)	−0.001 (2)	0.025 (2)	0.000 (2)
C11	0.057 (3)	0.061 (2)	0.057 (2)	0.000 (2)	0.024 (2)	0.0004 (19)
C12	0.068 (3)	0.064 (3)	0.066 (3)	−0.003 (2)	0.029 (2)	0.000 (2)
C13	0.076 (3)	0.070 (3)	0.067 (3)	0.000 (3)	0.034 (3)	0.007 (2)
C14	0.079 (3)	0.081 (3)	0.049 (2)	0.007 (3)	0.021 (2)	0.009 (2)
C15	0.070 (3)	0.070 (3)	0.060 (3)	−0.001 (2)	0.020 (2)	−0.001 (2)
C16	0.062 (3)	0.056 (2)	0.057 (2)	0.002 (2)	0.025 (2)	0.0017 (18)
C17	0.076 (3)	0.063 (3)	0.070 (3)	0.003 (2)	0.033 (3)	−0.001 (2)
C18	0.107 (5)	0.085 (3)	0.081 (4)	−0.009 (3)	0.044 (3)	−0.010 (3)
C19	0.132 (6)	0.106 (4)	0.096 (5)	0.003 (4)	0.063 (4)	−0.003 (4)
C20	0.134 (6)	0.110 (5)	0.079 (4)	0.016 (5)	0.042 (4)	−0.019 (4)
C21	0.119 (5)	0.096 (4)	0.099 (5)	−0.019 (4)	0.034 (4)	−0.035 (4)
C22	0.099 (4)	0.072 (3)	0.088 (4)	−0.016 (3)	0.038 (3)	−0.014 (3)
C23	0.074 (3)	0.076 (3)	0.081 (3)	−0.009 (3)	0.035 (3)	−0.005 (2)
C24	0.068 (3)	0.068 (3)	0.090 (4)	−0.008 (3)	0.031 (3)	−0.005 (3)
C25	0.081 (4)	0.075 (3)	0.101 (4)	−0.008 (3)	0.030 (3)	−0.008 (3)
C26	0.102 (5)	0.123 (5)	0.093 (4)	−0.012 (4)	0.010 (4)	−0.015 (4)
N1	0.064 (2)	0.0555 (19)	0.061 (2)	−0.0017 (17)	0.0238 (18)	0.0022 (16)
O1	0.062 (2)	0.084 (2)	0.088 (2)	0.0006 (18)	0.0117 (18)	−0.0075 (18)
O2	0.139 (3)	0.0680 (19)	0.077 (2)	0.000 (2)	0.045 (2)	0.0174 (17)
S1	0.0655 (8)	0.0998 (9)	0.0656 (7)	−0.0180 (7)	0.0261 (6)	−0.0056 (6)
S2	0.0822 (9)	0.0616 (6)	0.0625 (7)	0.0020 (6)	0.0229 (6)	0.0030 (5)
F1	0.114 (2)	0.107 (2)	0.0552 (16)	−0.0063 (19)	0.0187 (16)	0.0166 (15)