| Crystal data |
| Chemical formula |
[Mn(C7H9N)(H2O)5]SO4
|
[Co(C7H9N)(H2O)5]SO4
|
[Ni(C7H9N)(H2O)5]SO4
|
[Zn(C7H9N)(H2O)5]SO4
|
|
M
r
|
348.23 |
352.22 |
352.00 |
358.66 |
| Crystal system, space group |
Orthorhombic, P
n
m
a
|
Orthorhombic, P
n
m
a
|
Orthorhombic, P
n
m
a
|
Orthorhombic, P
n
m
a
|
| Temperature (K) |
297 |
297 |
297 |
297 |
|
a, b, c (Å) |
17.1868 (13), 7.1278 (5), 11.4447 (8) |
17.1238 (10), 7.1064 (4), 11.2576 (6) |
17.1196 (8), 7.0609 (3), 11.2233 (5) |
17.1312 (8), 7.0826 (3), 11.2879 (5) |
|
V (Å3) |
1402.02 (17) |
1369.92 (13) |
1356.67 (10) |
1369.60 (11) |
|
Z
|
4 |
4 |
4 |
4 |
| Radiation type |
Mo Kα |
Mo Kα |
Mo Kα |
Mo Kα |
| μ (mm−1) |
1.13 |
1.44 |
1.62 |
1.99 |
| Crystal size (mm) |
0.22 × 0.08 × 0.05 |
0.08 × 0.08 × 0.06 |
0.17 × 0.04 × 0.03 |
0.21 × 0.13 × 0.1 |
| |
| Data collection |
| Diffractometer |
Bruker D8 Venture CMOS |
Bruker D8 Venture CMOS |
Bruker D8 Venture CMOS |
Bruker D8 Venture CMOS |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2021 ▸) |
Multi-scan (SADABS; Bruker, 2021 ▸) |
Multi-scan (SADABS; Bruker, 2021 ▸) |
Multi-scan (SADABS; Bruker, 2021 ▸) |
|
T
min, T
max
|
0.585, 0.745 |
0.714, 0.745 |
0.680, 0.745 |
0.671, 0.745 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
27161, 1460, 1265 |
32289, 1367, 1194 |
36924, 1499, 1386 |
46710, 1516, 1414 |
|
R
int
|
0.074 |
0.070 |
0.049 |
0.042 |
| (sin θ/λ)max (Å−1) |
0.612 |
0.603 |
0.625 |
0.625 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.032, 0.081, 1.11 |
0.028, 0.069, 1.12 |
0.023, 0.060, 1.10 |
0.021, 0.056, 1.12 |
| No. of reflections |
1460 |
1367 |
1499 |
1516 |
| No. of parameters |
128 |
128 |
128 |
128 |
| No. of restraints |
7 |
7 |
7 |
7 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.39, −0.42 |
0.43, −0.29 |
0.44, −0.33 |
0.40, −0.27 |
