| Crystal data |
| Chemical formula |
[Ni(C6H6N3OS)2]·2CH4O |
|
M
r
|
459.19 |
| Crystal system, space group |
Triclinic, P
|
| Temperature (K) |
296 |
|
a, b, c (Å) |
6.5394 (11), 8.9611 (15), 10.2020 (15) |
| α, β, γ (°) |
67.965 (5), 79.666 (6), 70.349 (6) |
|
V (Å3) |
520.92 (15) |
|
Z
|
1 |
| Radiation type |
Mo Kα |
| μ (mm−1) |
1.16 |
| Crystal size (mm) |
0.26 × 0.21 × 0.12 |
| |
| Data collection |
| Diffractometer |
Bruker APEXII CCD |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2008 ▸) |
|
T
min, T
max
|
0.735, 0.861 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
8497, 2134, 1633 |
|
R
int
|
0.046 |
| (sin θ/λ)max (Å−1) |
0.626 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.032, 0.088, 1.04 |
| No. of reflections |
2134 |
| No. of parameters |
125 |
| H-atom treatment |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.25, −0.21 |
