Photophysical properties of the synthesized azodye derivatives 3a–o.
| Azodyes | Absorptiona, λmax/abs (nm) | ε max (M−1 cm−1) | Emissionb, λmax/em (nm) | Stokes shiftsc (nm) |
|---|---|---|---|---|
| 3a | 475 | 20 569 | 551 | 76 |
| 3b | 472 | 30 036 | 549 | 77 |
| 709 | 237 | |||
| 3f | 476 | 30 432 | 552 | 76 |
| 3i | 475 | 22 908 | 549 | 74 |
| 3j | 476 | 25 639 | 553 | 77 |
| 3m | 444 | 12 852 | 513 | 69 |
| 3o | 494 | 240 212 | 576 | 82 |
Determined in acetone at room temperature when the concentration of each compound is 1.0 × 10−5 M.
Excited at the longest wavelength of the absorption maxima.
Stokes shifts are provided as wavelength differences, Δλmax = λmax(em) − λmax(ex).