. 2023 Aug 3;88(16):11683–11693. doi: 10.1021/acs.joc.3c00980

Table 1. Comparison of Directly Determined and Extrapolated Mean Kinetic Rate Constants of Model System YND–BME 6a:d1-d3 in CDCl₃.

method	6a:d11 avg k (s^–1) t_1/2 (min)	6a:d2 avg k (s^–1) t_1/2 (min)	6a:d3 avg k (s^–1) t_1/2 (min)
direct	5.38 ± 0.18 × 10^–4	2.08 ± 0.20 × 10^–3	2.64 ± 0.32 × 10^–4
	21.5 ± 0.7	5.6 ± 0.5	44.0 ± 5.3
extrapolated	6.19 ± 0.53 × 10^–4	1.69 ± 0.67 × 10^–3	1.63 ± 0.37 × 10^–4
	18.7 ± 1.5	7.6 ± 3.8	73.9 ± 17.8

Table 1. Comparison of Directly Determined and Extrapolated Mean Kinetic Rate Constants of Model System YND–BME 6a:d1-d3 in CDCl3.