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. 2023 May 9;8(9):2223–2233. doi: 10.1039/d3re00113j

Species identified in the OES and their respective electronic transitions and intensities31.

Species Wavelength (nm) Transition Peak intensity
293 K 273 K
CO2+ 351 FDB, A2Π → X2 ((υ′, 0, 0) → (υ′′, 0, 0)) 74 95
94 78
367 77 81
385
CO2+ 434.2 FDB, A2Π → X2 ((υ′, 0, 0) → (υ′′, 0, 2)) 88 96
CO 471.7 Triplet system, d3Δ → a3Π 66 76
CO 451 Ångström system, B1Σ+–A1Π (0–0)a 258 288
483 B1Σ+–A1Π (0–1) 421 426
520 B1Σ+–A1Π (0–2) 555 549
561 B1Σ+–A1Π (0–3) 407 408
579 B1Σ+–A1Π (0–4) 216 227
610 Ångström system 164 162
O 751 3p5P → 3s5S0 177 124
777 316 305
178 190
845
a

The Angstrom system of CO from the electronic transition of B1Σ+ → A1Π of CO is attributed to the v′ = 0 vibrational level of the upper electronic state to vibrational levels (v′′ = 0, 1, 2, 3, and 4) of the lower electronic state.