Table 1. Photophysical Properties of QTCy7-R.
compd | λabs (nm)a | λem (nm)b | Δλ (nm)c | ΦF (%)d | τS (ns)e | ΦΔf |
---|---|---|---|---|---|---|
QTCy7-Me | 714 | 780 | 66 | 16.7 | 1.70 | 0.225 |
QTCy7-Ph | 711 | 783 | 72 | 17.2 | 1.90 | 0.212 |
QTCy7-CHO | 630 | 690 | 60 | 28.0 | 1.82 | 0.263 |
QTCy7-Ac | 636 | 703 | 67 | 31.4 | 1.97 | 0.338 |
TCy7 | 770 | 793 | 23 | 19.3 | 1.54 | 0.026 |
Maximum absorption wavelength of the compound in dichloromethane.
Maximum emission wavelength of the compound in dichloromethane.
Stokes shift of QTCy7-R.
Absolute fluorescence quantum yield.
Fluorescence lifetime of QTCy7-R in dichloromethane.
Singlet oxygen quantum yield in dichloromethane with methylene blue (MB) as the standard (ΦΔ = 0.57 in dichloromethane).