Table 1. Stationary Points Relative to the Reactants Asymptote in the APW⁴³ PES for Li + HF → LiF + H^a.

	Li + HF → LiF + H
	R(LiF)	R(HF)	∠LiFH	energy
reactants: Li + HF		0.917		0.0
well1: Li···H–F	4.192	0.922	0.0	–0.033
well2: Li···F–H	1.881	0.930	104.8	–0.243
saddle point	1.673	1.268	72.9	0.221
well3: Li–F···H	1.576	2.466	69.7	0.067
products: LiF + H	1.564			0.117

^aDistances in Å, energies in eV, and angles in deg. ∠LiFH = 180° corresponds to the linear Li–F–H arrangement.