Saturation capacity theoretically and experimentally estimated for MFI-140 and MFI-11.5.
| 1-Alcohol | Theory | Experiment | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| MFI | H-MFI-140 | H-MFI-11.5 | |||||||||
| N alcohol per UC | Adsorbed amount [mmol g−1] | Adsorbed volumea [mL g−1] | N alcohol per UC | N alcohol per BAS | N alcohol per BAS + defect sites | Adsorbed amount [mmol g−1] | Adsorbed volumea [mL g−1] | N alcohol per UC | N alcohol per BAS | N alcohol per BAS + defect sites | |
| Methanol | 23.9 | 4.07 | 0.17 | 23.8 | 58.2 | 33.9 | 4.25 | 0.17 | 24.8 | 4 | 2.6 |
| Ethanol | 16.5 | 3.12 | 0.18 | 18.2 | 44.5 | 26 | 3.00 | 0.18 | 17.6 | 2.9 | 1.8 |
| 1-Propanol | 12.6 | 2.34 | 0.18 | 13.7 | 33.5 | 19.5 | 1.96 | 0.15 | 11.4 | 1.9 | 1.2 |
| 1-Pentanol | 9.5 | 1.62 | 0.18 | 9.5 | 23.2 | 13.5 | 1.31 | 0.14 | 7.6 | 1.2 | 0.8 |
Assuming liquid-like packing of molecules.