Table 2. 31P NMR Shifts (δP in ppm) of Compounds 1 and 6a.
compound | δP | compound | δP | ΔδPc |
---|---|---|---|---|
1 | –16.4 | 6 | –9.7 | +6.7 |
1O | 29.3 | 6O | 39.1 | +9.8 |
1S | 41.9 | 6S | 41.4 | –0.5 |
1Se | 32.1 [735]b | 6Se | 31.8 [726]b | –0.3 |
The spectra were recorded in CDCl3 at 25 °C.
1JSeP coupling constant in Hz.
Chemical shift difference between 6 and 1.