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. 2023 Aug 10;62(34):14028–14043. doi: 10.1021/acs.inorgchem.3c02075

Table 2. 31P NMR Shifts (δP in ppm) of Compounds 1 and 6a.

compound δP compound δP ΔδPc
1 –16.4 6 –9.7 +6.7
1O 29.3 6O 39.1 +9.8
1S 41.9 6S 41.4 –0.5
1Se 32.1 [735]b 6Se 31.8 [726]b –0.3
a

The spectra were recorded in CDCl3 at 25 °C.

b

1JSeP coupling constant in Hz.

c

Chemical shift difference between 6 and 1.