Table 1.
Proposed solutions to addressing zinc dendrite issues in Zn-based rechargeable batteries
| Strategies | Materials | Principle | Function | Limitation |
|---|---|---|---|---|
| Additives into electrolytes |
Polymer (PEI, PEG, PVA) Organic molecules (Alcohols, DMSO) |
Adsorption on the zinc-based electrode surface |
Block the formation sites of zinc dendrites Slow down the depositing rate of zinc |
Increase the polarisation of zinc-based electrodes |
| Metal ions (Bi3+, Pb2+) | Substrate effect | Optimise the current distribution of electrodes | Influence the electrochemistry of flow batteries | |
| Additives into electrodes | Polymer (PTFE, PE) | Binder |
Reduce the generation sites of dendrites Decrease the solubility of zinc-based compounds |
NA |
| Metal oxides or metal hydroxides (PbO, In(OH)3) |
Substrate effect Alloying of Zn-based electrodes |
Optimise the current distribution of electrodes Regulate the deposition of Zn2+ |
Influence the FB electrochemistry HER issue of Zn alloy |
|
| Modification of the electrode structure | (3D) structure design | Improvement of zinc activity, stability and reversibility | Increasing the surface area of the electrodes to make a uniform deposition of zinc | NA |