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. 2023 Aug 31;15:209. doi: 10.1007/s40820-023-01174-7

Table 1.

Proposed solutions to addressing zinc dendrite issues in Zn-based rechargeable batteries

Strategies Materials Principle Function Limitation
Additives into electrolytes

Polymer (PEI, PEG, PVA)

Organic molecules (Alcohols, DMSO)

Adsorption on the zinc-based electrode surface

Block the formation sites of zinc dendrites

Slow down the depositing rate of zinc

Increase the polarisation of zinc-based electrodes
Metal ions (Bi3+, Pb2+) Substrate effect Optimise the current distribution of electrodes Influence the electrochemistry of flow batteries
Additives into electrodes Polymer (PTFE, PE) Binder

Reduce the generation sites of dendrites

Decrease the solubility of zinc-based compounds

NA
Metal oxides or metal hydroxides (PbO, In(OH)3)

Substrate effect

Alloying of Zn-based electrodes

Optimise the current distribution of electrodes

Regulate the deposition of Zn2+

Influence the FB electrochemistry

HER issue of Zn alloy

Modification of the electrode structure (3D) structure design Improvement of zinc activity, stability and reversibility Increasing the surface area of the electrodes to make a uniform deposition of zinc NA