The bond lengths of some bonds in the single Sb substitution systems of jamesonite.

Substitution systems	Bond type	Length (Å)
One Sb atom substitution	Sb1–S1 (Sb1–S3)	2.57
	Sb1–S2	2.67
	Fe2–S4	2.27
	Fe2–S5	2.20
Two Sb atoms substitution	Sb1–S1 (Sb1–S3)	2.60
	Sb1–S2	2.63
	Sb2–S4	2.63
	Sb2–S5	2.60
Three Sb atoms substitution	Sb1–S1 (Sb1–S3)	2.59
	Sb1–S2	2.64
	Fe2–S4	2.29
	Fe2–S5	2.20
	Sb3–S6	2.65
	Sb4–S7 (Sb3–S9)	2.64
	Sb4–S8	2.63