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. 2023 Sep 11;14:5589. doi: 10.1038/s41467-023-41440-1

Table 2.

Photophysical, thermal, and surface properties of doped films

2 wt% ν-DABNA-doped film Tgc (°C) Tdd (°C) RMSe (nm)
θ//a (%) PLQY τd b (μs) λmax/FWHM (nm) kRISC (105 s−1)
TDBA-Ph 84 0.82 2.99 469/18 2.25 62 255 1.65
mTDBA-Ph 78 0.93 2.76 469/18 3.13 58 230 1.42
mTDBA-2Ph 86 0.86 1.86 468/18 3.98 93 262 1.78
TDBA-Si 91 0.82 0.96 469/18 7.01 130 324 0.37
mTDBA-Si 88 0.94 1.93 469/18 4.58 122 348 0.47
mTDBA-2Si 89 0.92 0.98 468/18 8.64 180 403 0.66

aHorizontal transient dipole orientation ratio.

bDelayed lifetime calculated by photoluminescence decay.

cGlass transition temperature.

dDecomposition temperature.

eRoot mean square roughness measured by atomic force microscopy (AFM).