Table 1. Scope of the Photoinduced Nitroarene Promoted Oxidation of (A) Alcohols and Amines as Well as (B) Aldehydes and Iminesa.
Conditions B.
Using 2-bromo-4-nitropyridine.
Under 390 nm.
In MeCN/H2O (1:1, 0.3 M).
No LiOAc.
Denotes 1H NMR yield using CH2Br2 as an internal standard.
Isolated as a hydrazone derivative (see SI).
Denotes 1H NMR yield using CH2Cl2 as an internal standard.
MeCN (1 M).
H2O (1.0 equiv).
Neat.