Table 2.
EIS parameters for the carbon steel in 1.0 M HCl in the absence and presence of different concentrations of the inhibitor compounds.
| Inhibitor | Conc. (M) | Rs (Ω cm2) | Rct (Ω cm2) | Q (μ Ω–1 sn cm–2) | n | Cdl (μF cm–2) | Chi squared (χ2) | S | α° | θ | ηz % |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Blank | – | 4.699 | 91.21 | 1215.00 | 0.8632 | 857.368 | 3.34 × 10–3 | − 0.572 | − 55.20 | – | – |
| DHSiMF | 5 × 10–6 | 2.562 | 552 | 214.10 | 0.7165 | 91.971 | 9.89 × 10–3 | − 0.640 | − 56.79 | 0.835 | 83.48 |
| 1 × 10–4 | 2.205 | 640.5 | 363.90 | 0.6297 | 154.538 | 1.76 × 10–2 | − 0.570 | − 51.29 | 0.858 | 85.76 | |
| 1 × 10–3 | 3.021 | 683.2 | 102.60 | 0.7777 | 47.995 | 8.87 × 10–3 | − 0.701 | − 63.75 | 0.866 | 86.65 | |
| 5 × 10–3 | 2.551 | 1183 | 105.40 | 0.7679 | 56.176 | 7.49 × 10–3 | − 0.716 | − 62.80 | 0.923 | 92.29 | |
| 1 × 10–2 | 2.816 | 3126 | 52.29 | 0.8024 | 33.474 | 6.95 × 10–3 | − 0.770 | − 66.78 | 0.971 | 97.08 | |
| DHSiB | 5 × 10–6 | 2.626 | 468.4 | 341.70 | 0.674 | 140.852 | 1.13 × 10–2 | − 0.573 | − 52.08 | 0.805 | 80.53 |
| 1 × 10–4 | 3.126 | 606.1 | 128.40 | 0.7774 | 61.808 | 6.26 × 10–3 | − 0.676 | − 60.57 | 0.850 | 84.95 | |
| 1 × 10–3 | 2.753 | 666 | 151.20 | 0.7697 | 76.076 | 8.38 × 10–3 | − 0.671 | 62.10 | 0.863 | 86.30 | |
| 5 × 10–3 | 3.172 | 1059 | 469.60 | 0.5975 | 293.334 | 1.71 × 10–2 | − 0.460 | 51.48 | 0.914 | 91.39 | |
| 1 × 10–2 | 2.953 | 1735 | 82.85 | 0.7818 | 48.214 | 5.82 × 10–3 | − 0.724 | − 65.67 | 0.947 | 94.74 |