Table 6.
Activation parameters of dissolution reaction of carbon steel in 1 M HCl with at different concentrations of inhibitor compounds.
| Inhibitor | Conc. of inhibitors (M) | Ea (kJ mol–1) | ∆H* (kJ mol–1) | ∆S* (J mol–1 K–1) |
|---|---|---|---|---|
| Blank | 0.00 × 10–4 | 16.09 | 13.17 | – 207.90 |
| DHSiMF | 5 × 10–6 | 40.42 | 36.99 | − 141.04 |
| 1 × 10–4 | 42.91 | 39.43 | − 133.68 | |
| 1 × 10–3 | 47.91 | 43.68 | − 120.99 | |
| 5 × 10–3 | 48.86 | 45.26 | − 116.29 | |
| 1 × 10–2 | 50.89 | 47.24 | − 110.25 | |
| DHSiB | 5 × 10–6 | 37.15 | 33.78 | − 150.29 |
| 1 × 10–4 | 38.89 | 35.50 | − 145.37 | |
| 1 × 10–3 | 40.91 | 37.47 | − 139.80 | |
| 5 × 10–3 | 42.44 | 38.97 | − 135.66 | |
| 1 × 10–2 | 45.70 | 42.16 | − 126.04 |