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. 2023 Sep 12;13:15091. doi: 10.1038/s41598-023-41165-7

Table 6.

Activation parameters of dissolution reaction of carbon steel in 1 M HCl with at different concentrations of inhibitor compounds.

Inhibitor Conc. of inhibitors (M) Ea (kJ mol–1) ∆H* (kJ mol–1) ∆S* (J mol–1 K–1)
Blank 0.00 × 10–4 16.09 13.17 – 207.90
DHSiMF 5  ×  10–6 40.42 36.99  − 141.04
1 × 10–4 42.91 39.43  − 133.68
1 × 10–3 47.91 43.68  − 120.99
5 × 10–3 48.86 45.26  − 116.29
1 × 10–2 50.89 47.24  − 110.25
DHSiB 5 × 10–6 37.15 33.78  − 150.29
1 × 10–4 38.89 35.50  − 145.37
1 × 10–3 40.91 37.47  − 139.80
5 × 10–3 42.44 38.97  − 135.66
1 × 10–2 45.70 42.16  − 126.04