Figure 2.

a) Crystal packing diagram of (S)‐DNTT in the herringbone plane without the chiral alkyl chains. Molecules in pink and red are crystallographically independent one with respect to the other. The black dashed lines represent S–S short contacts, the herringbone angle is displayed in grey. b) (S)‐DNTT intermolecular transfer integrals (in meV) calculated from the experimental crystal structure. c) Front view of the Hirshfeld surfaces of the two distinct molecules belonging to the same unit cell of (S)‐DNTT with S–S contact regions highlighted in yellow.