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. 2023 Sep 19;13(40):27764–27771. doi: 10.1039/d3ra01025b

Ring-opening reactions of 1b with different catalysts and equimolar alcohols Ax.

Runa Alcohol Catalyst Loadingb (equiv.) Solvent 2(Ax) : 2bc
1 A1 DPP 0.1 Toluene 100 : 0
2 A2 DPP 0.1 Toluene 55 : 45
3 A3 DPP 0.1 Toluene 55 : 45
4 A3 DPP 0.1 CHCl3 3 : 97
5 A3 TU/DBU 0.02, 0.02 Toluene 0 : 100
6 A3 TU/DBU 0.02, 0.02 CHCl3 0 : 100
7 A3 Sn(Oct)2 0.02, 0.02 Toluene 0: 100
8 A3 Sn(Oct)2 0.02, 0.02 CHCl3 0 : 100
a

All reactions were conducted for 1 h at 20–25 °C (room temperature).

b

Relative to 1b.

c

Determined using 1H NMR.