Table 2. Enthalpies of Dissolution in 5 N HCl at 25 °C and Enthalpies of Formation of BIFs from the Metal Oxide and Linker.
| Sample | BET Surface Area (m2·g–1) | ΔHdis (kJ·mol–1) | ΔH°f (kJ·mol–1) |
|---|---|---|---|
| HB(MeIm)4 | –144.42 ± 0.43 (4) | ||
| H2O22 | –0.5 | ||
| Li2Oa | –254.036 ± 0.27 (5) | ||
| Ag2O | –185.32 ± 0.60 (6) | ||
| Cu2O | –246.80 ± 0.59 (5) | ||
| dia-LiB(MeIm)4 | –176.82 ± 0.66 (5) | –94.35 ± 0.97 | |
| dia-AgB(MeIm)4 | –137.54 ± 0.62 (5) | –99.28 ± 0.96 | |
| SOD-AgB(MeIm)4 | 10204 | –186.93 ± 0.28 (5) | –49.89 ± 0.79 |
| SOD-CuB(MeIm)4 | 9354 | –206.48 ± 0.72 (5) | –61.07 ± 1.02 |
a
Enthalpy of dissolution of Li2O is calculated from dissolution of Li2CO3. Error is reported as two standard deviations from the mean. Value in parentheses represents the number of experiments.