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. Author manuscript; available in PMC: 2023 Sep 22.
Published in final edited form as: Environ Sci Technol. 2020 Aug 4;54(16):9769–9790. doi: 10.1021/acs.est.0c01666

Table 3.

Commonly Used Metrics to Quantify Selectivity

Eqn # Relationship Definition of Terms Ref(s)
1 %R=(C0Ce)C0x100% %R is percent removal, C0 is the initial concentration of the adsorbate (ppm)
Ce is the equilibrium concentration of the adsorbate (ppm)
15,112
2 q=vm(C0Ce) q is the equilibrium adsorption capacity for a target contaminant (mg/g), v is the volume of adsorbate solution (mL), and m is the mass of adsorbent (mg) 110
3 %I=qtqt+c %I is percent interference, qt is the adsorption capacity for the target contaminant and qt+c is the adsorption capacity for the target contaminant with a competitive oxo-anion present. 113
4 Adsorption capacity ratio%=qtqt+cx100% 114
5 t/c=qtCe,cqcCe,t t/c is the binary separation factor for the adsorption of target oxoanion, t, in the presence of competitive oxo-anion, c, Ce,c is the equilibrium concentration of the competitive oxoanion in the mixed ion system, and Ce,t is the equilibrium concentration of the target oxoanion in the mixed ion system. 11,24,29,79,110,114119
6 Kd=C0CeCexvm Kd is the distribution coefficient, C0 the initial concentration of the target oxo-anion, and Ce the equilibrium concentration 120123
7 βt=Kd,tKd,c βt is the selectivity coefficient for the target anion, Kd,tis the distribution coefficient for the target ion with a competitor present, and Kd,c is the distribution coefficient for the competitor with the target ion present 124127