Table 3. Kinetic Parameters Acquired from the Second-Order Extraction Models.

methods–substances	temperature (°C)	Ce (mg/g)	h (mg/g min)	k (g/mg min)	R2	Ea (kJ/mol)	ln Ae	R2	ΔH (kJ/mol)	ΔG (kJ/mol)	ΔS (kJ/mol)
UAE–phenolics	30	30.5	9.1	0.010	0.948	33.1	8.40	0.888	30.58	11.64	0.06
	60	37.9	27.4	0.019	0.987				30.33	10.95	0.06
	80	23.8	39.8	0.070	0.989				30.17	7.79	0.06
UAE–flavonoids	30	14.2	22.0	0.109	0.951	10.5	1.96	0.826	7.98	5.58	0.01
	60	20.2	52.1	0.128	0.910				7.73	5.69	0.01
	80	17.3	61.7	0.206	0.989				7.57	4.64	0.01
MAE–phenolics	45	8.8	14.3	0.187	0.971	45.0	15.17	0.895	42.36	4.43	0.12
	70	17.2	106.4	0.358	0.982				42.15	2.93	0.11
	90	13.9	322.6	1.658	0.979				41.98	–1.53	0.12
MAE–flavonoids	45	6.9	19.2	0.399	0.999	37.4	13.12	0.946	34.76	2.43	0.10
	70	8.3	54.9	0.794	0.990				34.55	0.66	0.10
	90	6.3	94.3	2.403	0.996				34.38	–2.64	0.10