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Solid-state structure of compounds 3 (left) and 4 (right) with thermal ellipsoids at 30% of probability. Hydrogens are omitted for clarity. The torsion angle for cent1–cent2–Ti1–Cl1 is 58.98(1)° for 3 and 1.61(3)° for 4, where cent1 = centroid of diazametallacycle LiN2C2 and cent2 = centroid of the C2α-C2α′ ring. The dihedral angle between planes formed by C2β–C2α–C2α′–C2β′ and C2β–C2γ–C2γ′–C2β′ is 21.1(1)° for 3 and 14.4(3)° for 4.
