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. Author manuscript; available in PMC: 2023 Sep 27.
Published in final edited form as: Inorg Chem. 2023 Aug 16;62(34):14010–14027. doi: 10.1021/acs.inorgchem.3c02048

Scheme 1.

Scheme 1.

Outline of key findings from this comprehensive spectroscopic, electrochemical, and computational study of NiII precatalysts for enantioselective reductive alkenylation. FMO = frontier molecular orbital.