Table 8.
Silver catalyzed decarboxylation of α-fluoroacrylic acids to disubstituted vinyl fluorides.a
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Assay yields from 19F NMR versus PhCF3 are given in brackets, isolated yields are given with no brackets. E/Z isomeric purity of isolated product is given under yields. Isomeric purity determined by 19F NMR. For detailed reaction conditions, see the Experimental Section.
AgOAc loading of 50 mol %.