Photocatalytic selective oxidation of biomass-relevant alcohols over CdS–PdxS icosapods under visible-light irradiation (λ > 420 nm).
Entry | Substrate | Product | Conversion (%) | Selectivity (%) | H2 (μmol) | Reaction time (h) |
---|---|---|---|---|---|---|
1 | 98.1 | 99.1 | 95.9 | 2 | ||
2 | 98.6 | 99.7 | 96.5 | 2 | ||
3 | 98.3 | 99.8 | 96.3 | 2 | ||
4 | 97.6 | 99.7 | 95.0 | 2.5 | ||
5 | 98.8 | 99.3 | 96.4 | 4 | ||
6 | 47.8 | 94.8 | 42.9 | 8 | ||
7 | 89.7 | 99.3 | 85.8 | 6 | ||
8 | 23.9 | 90.4 | 22.2 | 24 |