Table 5.
RT | RIlit | RIcalc | Ref. RIlit | Match Factor |
Prob (%) |
Compounds | Extract | Phytosomes |
---|---|---|---|---|---|---|---|---|
7.47 | 1041 | 1059 | Silva et al. [57] | 972 | 93.8% | 1,8-Cineole | 0.613 ± 0.05 | 0.224 ± 0.04 |
10.91 | 1143 | 1131 | Radulovic et al. [58] | 950 | 67.2% | L-Pinocarveol | 0.097 ± 0.007 | 0.030 ± 0.005 |
11.65 | 1140 | 1114 | Muselli et al. [59] | 883 | 68.6% | Pinocarvone | 0.016 ± 0.003 | nd |
11.76 | 1170 | 1166 | Al-Omar [60] | 923 | 63.9% | Borneol | 0.0081 ± 0.001 | nd |
12.54 | 1172 | 1143 | Boti et al. [61] | 952 | 74.5% | α-Terpineol | 0.0894 ± 0.04 | 0.0233 ± 0.003 |
23.04 | 1567 | 1530 | Babushok et al. [62] | 929 | 55.5% | Globulol | 0.011 ± 0.002 | 0.0012 ± 0.001 |
33.78 | 2099 | 2045 | Babushok et al. [62] | 894 | 81.2% | Phytol | 0.1714 ± 0.03 | 0.0637 ± 0.01 |
45.04 | 2847 | 2914 | Zhao et al. [63] | 963 | 50.4% | Squalene | 0.1041 ± 0.01 | 0.0044 ± 0.001 |
53.66 | - | 2886 | - | 886 | 59.9% | Unknown 1 | 0.0957 ± 0.02 | 0.0364 ± 0.006 |
54.94 | - | 2848 | - | 941 | 86.5% | Unknow 2 | 0.8505 ± 0.05 | 0.2187 ± 0.03 |
RT retention time (min). RIlit retention index (iu) reported in the literature for 5% phenyl polysilphenylene-siloxane GC column. RIcalc retention index obtained through the modulated chromatogram. Ref. RIlit retention index bibliography found in the literature for 5% phenyl polysilphenylene-siloxane GC column. Extract (mg/mL), phytosomes (mg/mL). nd = Not detected. Non-polar retention index (n-alkane scale). The values are the mean ± SD (n = 3). Fragment ions (m/z) of unknown 1: 218 (100), 203, 219, 69, 95, 426 [M+], 411.4. Unknown 2: 189 (100, 95,207,93,135, 426 [M+], 411.4.