Table 1. Characteristic Molecular Orientation (MO) Order Parameters for Each Crystallographic Phase of MAPbBr3, Including the Alignment Factor (AF) and Contrast Factor (CF)a.
| MO order
parameters |
||||
|---|---|---|---|---|
| phases | AFa | AFb | AFc | CF |
| [↑↑↑↑...] | 1.0 | 1.0 | ||
| [↑↓↑↓...] | –1.0 | –1.0 | ||
| α, 350 K | –0.05 | –0.05 | –0.05 | 0.9 |
| β, 185 K | 0.05 | 0.05 | –0.25 | 0 |
| γ, 100 K | –0.40 | 0.75 | –1 | –0.75 |
Values for a 1D rod of aligned and anti-aligned molecules are shown for comparison.