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. 2023 Aug 30;127(38):19141–19151. doi: 10.1021/acs.jpcc.3c03377

Table 1. Characteristic Molecular Orientation (MO) Order Parameters for Each Crystallographic Phase of MAPbBr3, Including the Alignment Factor (AF) and Contrast Factor (CF)a.

  MO order parameters
phases AFa AFb AFc CF
[↑↑↑↑...] 1.0     1.0
[↑↓↑↓...] –1.0     –1.0
α, 350 K –0.05 –0.05 –0.05 0.9
β, 185 K 0.05 0.05 –0.25 0
γ, 100 K –0.40 0.75 –1 –0.75
a

Values for a 1D rod of aligned and anti-aligned molecules are shown for comparison.