Skip to main content
. 2023 Aug 22;13(19):5702–5709. doi: 10.1039/d3cy00704a

Hydrolysis of methyl benzoate by MINP catalysts in a 25 mM HEPES buffer (pH 7.0) after 4 h at 40 °Ca.

Entry Catalyst Yield (%)
1 MINP(4a·5a + 8) 85 ± 2
2 MINP(4b·5a + 8) 72 ± 2
3 MINP(4c·5a + 8) 46 ± 1
4 MINP(4d·5a + 8) 34 ± 2
5 MINP(4e·5a + 8) <5
6 MINP(4a·5b + 8) 55 ± 2
7 NINP <5
a

The conversion yields were determined by GC-MS analysis with p-xylene (600 μM) as the internal standard. [Methyl benzoate] = 600 μM. [MINP] = 15 μM.